Laser assisted sampling vs direct desorption flowing atmospheric pressure afterglow mass spectrometry of complex polymer samples: Forensic implications for pressure sensitive tape chemical analysis.

Flowing atmospheric pressure afterglow (FAPA) mass spectrometry (MS) is an easy-to-use, cost-effective, and potentially portable technique that allows direct desorption/ionization from samples with little-to-no sample preparation for real-time chemical analysis. However, it has limitations regarding analytes with low desorption efficiency, such as polymers. Here, laser assisted sampling (LAS) is developed and coupled to FAPA MS to allow access to a wider range of chemical information from polymer samples.