Distribution and mobility of arsenic in the Río Dulce alluvial aquifers in Santiago del Estero Province, Argentina.

Factors controlling arsenic (As) mobilization in the aquifers of the Río Dulce alluvial cone were investigated. Groundwater analyses show severe As contamination (average concentration of 743 mug/L) from geogenic sources, but spatial variability of As concentration is considerable. Sequential leaching of sediment samples from unsaturated zone using de-ionised water, bicarbonate, acetate, and oxalate extracted As to different extents.