Ecologically based methods for promoting safer nanosilver for environmental applications.

Nanosilver, widely employed in consumer products as biocide, has been recently proposed as sensor, adsorbent and photocatalyst for water pollution monitoring and remediation. Since nanosilver ecotoxicity still pose limitations to its environmental application, a more ecological exposure testing strategy should be coupled to the development of safer formulations. Here, we tested the environmental safety of novel bifunctionalized nanosilver capped with citrate and L-cysteine (AgNPcitLcys) as sensor/sorbent of Hg in terms of behaviour and ecotoxicity on microalgae (1-1000 µg/L) and microcrustaceans (0.