Publications by authors named "Matthieu Rivallin"

The development of new photoanode materials for hydrogen production and water treatment is in full progress. In this context, hybrid TiO-CoO/Co(OH) photoanodes prepared using the sol-gel method using biosurfactants are currently being developed by our group. The combination of TiO with a cobalt-based compound significantly enhances the visible absorption and electrochemical performance of thin films, which is mainly due to an increase in the specific surface area and a decrease in the charge transfer resistance on the surface of the thin films.

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Electro-oxidation of acetaminophen (ACT) in three different doped secondary effluents collected from a conventional Municipal Waste Water Treatment Plant (MWWTP), a MWWTP using a membrane bioreactor (WWTP MBR) and a lab-scale MBR treating source-separated urine (Urine MBR) was investigated by electro-Fenton (EF) coupled with anodic oxidation (AO) using sub-stoichiometric titanium oxide anode (TiO). After 8 h of treatment, 90 ± 15%, 76 ± 3.8% and 46 ± 1.

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The objective of this study was to implement electrochemical advanced oxidation processes (EAOPs) for mineralization and biodegradability enhancement of nanofiltration (NF) concentrate from landfill leachate initially pre-treated in a membrane bioreactor (MBR). Raw carbon felt (CF) or FeFe layered double hydroxides-modified CF were used for comparing the efficiency of homogeneous and heterogeneous electro-Fenton (EF), respectively. The highest mineralization rate was obtained by heterogeneous EF: 96% removal of dissolved organic carbon (DOC) was achieved after 8 h of electrolysis at circumneutral initial pH (pH = 7.

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Reactive Electrochemical Membrane (REM) prepared from carbothermal reduction of TiO is used for the mineralization of biorefractory pollutants during filtration operation. The mixture of TiO and TiO Magnéli phases ensures the high reactivity of the membrane for organic compound oxidation through OH mediated oxidation and direct electron transfer. In cross-flow filtration mode, convection-enhanced mass transport of pollutants can be achieved from the high membrane permeability (3300 LMH bar).

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Metal oxides and metal oxide/carbon composites are entering the development of new technologies and should therefore to be prepared by sustainable chemistry processes. Therefore, a new aspect of the reactivity of cellulose is presented through its solid/gas reaction with vapour of titanium(IV) chloride in anhydrous conditions at low temperature (80 °C). This reaction leads to two transformations both for cellulose and titanium(IV) chloride.

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The bactericidal activity of an Al2O3-TiO2-Ag granular material against an Escherichia coli strain was confirmed by a culture-based method. In particular, 100% of microorganisms were permanently inactivated in 30 to 45 min. The present work aimed to investigate the mechanisms of the bactericidal action of this material and their dynamics on Escherichia coli using different techniques.

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