Publications by authors named "Matthew W Sima"

Advances in biological degradation of per- and polyfluoroalkyl substances (PFAS) have shown that bioremediation is a promising method of PFAS mineralization; however, most of these studies focus on remediation of more reactive polyfluorinated compounds. This review focuses on the defluorination of the more recalcitrant perfluorinated alkyl acids (PFAAs) by bacteria. We highlight key studies that report PFAA degradation products, specific bacteria, and relevant genes.

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Per- and polyfluoroalkyl substances (PFAS) are emerging contaminants of concern due to their health effects and persistence in the environment. Although perfluoroalkyl acids (PFAAs), such as perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) are very difficult to biodegrade because they are completely saturated with fluorine, it has recently been shown that Acidimicrobium sp. A6 (A6), which oxidizes ammonium under iron reducing conditions (Feammox process), can defluorinate PFAAs.

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Due to their health effects and the recalcitrant nature of their CF bonds, Poly- and Perfluoroalkyl Substances (PFAS) are widely investigated for their distribution, remediation, and toxicology in ecosystems. However, very few studies have focused on modeling PFAS in the soil-water environment. In this review, we summarized the recent development in PFAS modeling for various chemical, physical, and biological processes, including sorption, volatilization, degradation, bioaccumulation, and transport.

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