Tracking the heat-triggered phase change of polydopamine-shelled, perfluorocarbon emulsion droplets into microbubbles using neutron scattering.

Perfluorocarbon emulsion droplets are hybrid colloidal materials with vast applications, ranging from imaging to drug delivery, due to their controllable phase transition into microbubbles via heat application or acoustic droplet vapourisation. The current work highlights the application of small- and ultra-small-angle neutron scattering (SANS and USANS), in combination with contrast variation techniques, in observing the in situ phase transition of polydopamine-shelled, perfluorocarbon (PDA/PFC) emulsion droplets with controlled polydispersity into microbubbles upon heating. We correlate these measurements with optical and transmission electron microscopy imaging, dynamic light scattering, and thermogravimetric analysis to characterise these emulsions, and observe their phase transition into microbubbles.

Rich liquid crystal phase behavior of novel alkyl-tri(ethylene glycol)-glucoside carbohydrate surfactants.

Carbohydrates are appealing non-ionic surfactant head-groups as they are naturally abundant, generally biocompatible and biodegradable, and readily functionalized. Herein, we explore the phase behavior of seven novel carbohydrate-based surfactants (CBS) containing a tri-ethylene glycol (TEG) linker between a glucose head-group and alkyl tail-group, with linear saturated (C8-18) and cis-unsaturated (C18:1) alkyl chains. At high aqueous concentrations, these glycolipid-like surfactants transition into a variety of lyotropic liquid crystalline phases following an expected concentration phase sequence: hexagonal (H) → bicontinuous cubic (V) → lamellar (L).

Structural and rheological changes of lamellar liquid crystals as a result of compositional changes and added silica nanoparticles.

Lamellar liquid crystals comprising oil, water and surfactant(s) were formulated and analysed in order to examine how these materials responded to the inclusion of inorganic nanoparticles, in terms of their structural and rheological characteristics. Lamellar phases were formed from mixtures of water, para-xylene and Triton X-100, and analysis was performed via small-angle neutron scattering (SANS), polarising light microscopy (PLM), and amplitude and viscosity sweeps. The partial replacement of Triton X-100 with oleic acid appeared to cause an increase in bilayer thickness, attributed to less efficient packing of the different molecules.

Structural Evolution of Wormlike Micellar Fluids Formed by Erucyl Amidopropyl Betaine with Oil, Salts, and Surfactants.

Solutions of extended, flexible cylindrical micelles, often known as wormlike micelles, have great potential as the base for viscoelastic complex fluids in oil recovery, drilling, and lubrication. Here, we study the morphology and nanostructural characteristics of a model wormlike micellar fluid formed from erucyl amidopropyl betaine (EAPB) in water as a function of a diverse range of additives relevant to complex fluid formulation. The wormlike micellar dispersions are extremely oleo-responsive, with even as little as 0.

The effects of alkylammonium counterions on the aggregation of fluorinated surfactants and surfactant ionic liquids.

The effects of organic counterions with varying carbon number on surfactant aggregation have been analysed by coupling perfluorooctanoate surfactant anions with various alkylammonium counterions. Both the degree of substitution (primary to tertiary) and alkyl chain length (0-3 carbons) of the counterions were varied to provide a comprehensive matrix of geometries and lipophilicities. Surface activity was measured using pendant drop tensiometry, while temperature-controlled small-angle neutron scattering was used to probe changes in aggregation morphology.

Light-induced structural evolution of photoswitchable carbohydrate-based surfactant micelles.

We report the light-induced structural evolution of photoswitchable carbohydrate-based surfactant micelles using time-resolved small-angle neutron scattering (TR-SANS), monitoring the structural changes in micellisation in situ over time and demonstrating for the first time the course and implications of this process.

Controlling the characteristics of lamellar liquid crystals using counterion choice, fluorination and temperature.

The characteristics of robust and highly ordered fluorinated lamellar phases were explored as a function of temperature, counterion identity and fluorination of the surfactant and co-surfactant. Structural and composition effects were probed using a combination of small-angle scattering of X-rays and neutrons, polarising microscopy and calorimetry. It was found that in general, the phases remained remarkably stable with increasing temperature, showing only moderate loss of order and increased membrane flexibility.

Reversible pH- and photocontrollable carbohydrate-based surfactants.

The parallel synthesis and properties of a library of photoswitchable surfactants comprising a hydrophobic butylazobenzene tail-group and a hydrophilic carbohydrate head-group, including the first surfactants to exhibit dual photo- and pH-responsive behavior, is reported. This new generation of surfactants shows varying micelle morphologies, photocontrollable surface tension, and pH-induced aggregation and adsorption.

Fluorinated lamellar phases: structural characterisation and use as templates for highly ordered silica materials.

Highly ordered silica was synthesised by using a lamellar phase comprising the anionic fluorinated surfactant sodium perfluorooctanoate and the partially-fluorinated co-surfactant/oil 1H,1H,2H,2H-perfluorooctan-1-ol in water. The phase behaviour of this system was thoroughly analysed, and it was found that even low levels of the alcohol (<0.5 mol%) were sufficient to induce a phase change from normal micelles to a lamellar phase, rationalised as a result of geometric and electrostatic effects.