Tabletop imaging of structural evolutions in chemical reactions demonstrated for the acetylene cation.

The introduction of femto-chemistry has made it a primary goal to follow the nuclear and electronic evolution of a molecule in time and space as it undergoes a chemical reaction. Using Coulomb Explosion Imaging, we have shot the first high-resolution molecular movie of a to and fro isomerization process in the acetylene cation. So far, this kind of phenomenon could only be observed using vacuum ultraviolet light from a free-electron laser.

Wavelength scaling of terahertz generation by gas ionization.

Low-frequency currents induced by ultrashort laser-driven ionization can emit extremely broadband, single-cycle terahertz pulses. We present a model that predicts a strong wavelength dependence of the THz emission in good agreement with our experimental study. This reveals that the combined effects of plasma currents rising proportionally to the square of the pump wavelength and wavelength-dependent focusing conditions lead to 30 times higher THz emission at 1800 nm compared to an 800 nm wavelength.

N2O ionization and dissociation dynamics in intense femtosecond laser radiation, probed by systematic pulse length variation from 7 to 500 fs.

We have made a series of measurements, as a function of pulse duration, of ionization and fragmentation of the asymmetric molecule N2O in intense femtosecond laser radiation. The pulse length was varied from 7 fs to 500 fs with intensity ranging from 4 × 10(15) to 2.5 × 10(14) W∕cm(2).

Pulse compression of submillijoule few-optical-cycle infrared laser pulses using chirped mirrors.

We report generation of 400 microJ, 13.1 fs, 1425 nm optical parametric amplifier laser pulses. Spectral broadening of a 100 Hz optical parametric amplifier laser source is achieved by self-phase modulation in an argon-filled hollow-core fiber, and dispersion compensation is performed using chirped mirrors.