Kinetics of competing exchange of oxygen and water at the surface of functional oxides.

The presence of water vapour in the input gas stream influences the performance of air electrodes of solid oxide cells. In this work, the oxygen transport kinetics were determined by isotopic exchange depth profiling at 350 °C on polycrystalline La0.6Sr0.

Back-exchange: a novel approach to quantifying oxygen diffusion and surface exchange in ambient atmospheres.

A novel two-step Isotopic Exchange (IE) technique has been developed to investigate the influence of oxygen containing components of ambient air (such as HO and CO) on the effective surface exchange coefficient (k*) of a common mixed ionic electronic conductor material. The two step 'back-exchange' technique was used to introduce a tracer diffusion profile, which was subsequently measured using Time-of-Flight Secondary Ion Mass Spectrometry (ToF-SIMS). The isotopic fraction of oxygen in a dense sample as a function of distance from the surface, before and after the second exchange step, could then be used to determine the surface exchange coefficient in each atmosphere.