Unlocking Low-Temperature Ammonia Decomposition via an Iron Metal-Organic Framework-Derived Catalyst Under Photo-Thermal Conditions.

Photo-thermal catalysis, leveraging both thermal and non-thermal solar contributions, emerges as a sustainable approach for fuel and chemical synthesis. In this study, an Fe-based catalyst derived from a metal-organic framework is presented for efficient photo-thermal ammonia (NH) decomposition. Optimal conditions, under light irradiation without external heating, result in a notable 55% NH conversion.

Ammonia Decomposition via MOF-Derived Photothermal Catalysts.

Three cobalt-based metal-organic framework (MOF)-derived catalysts were developed for photothermal hydrogen production via ammonia decomposition. The selected MOFs were from distinct families, featuring carboxylate and imidazole linkers, and diverse in terms of porosity. The resulting catalysts consisted of uniform and homogeneously dispersed cobalt nanoparticles embedded within a carbon matrix.

Gut Microbiota Alterations in Alzheimer's Disease: Relation with Cognitive Impairment and Mediterranean Lifestyle.

Recently, an association between dysbiosis of the gut microbiota (GMB) and the development of several diseases, such as Alzheimer's disease (AD), has been proposed. Dysbiosis involves changes in microbial diversity influenced by environmental factors, like diet or lifestyle. In this study, we investigated the role of GMB parameters in Spanish AD patients, assessing the impact of adherence to the Mediterranean lifestyle (ML), as well as to characterize these parameters in relation to neuropsychological, neuropsychiatric, emotional, and functionality parameters.

Urban dynamics through the lens of human mobility.

The urban spatial structure represents the distribution of public and private spaces in cities and how people move within them. Although it usually evolves slowly, it can change quickly during large-scale emergency events, as well as due to urban renewal in rapidly developing countries. Here we present an approach to delineate such urban dynamics in quasi-real time through a human mobility metric, the mobility centrality index ΔKS.

Influence of gut microbiota on the development of most prevalent neurodegenerative dementias and the potential effect of probiotics in elderly: A scoping review.

Dementia is one of today's greatest public health challenges. Its high socio-economic impact and difficulties in diagnosis and treatment are of increasing concern to an aging world population. In recent years, the study of the relationship between gut microbiota and different neurocognitive disorders has gained a considerable interest.

Cross-cultural adaptation of the FRAIL scale for critically ill patients in Spain.

Aim: To translate and culturally adapt the FRAIL scale into Spanish and perform a preliminary test of diagnostic accuracy in patients admitted to intensive care units.

Design: Cross-sectional diagnostic study.

Methods: Five intensive care units (ICU) in Spain were participated.

Aging Compensation in a Class-A High-Frequency Amplifier with DC Temperature Measurements.

One of the threats to nanometric CMOS analog circuit reliability is circuit performance degradation due to transistor aging. To extend circuit operating life, the bias of the main devices within the circuit must be adjusted while the aging degradation process affects them by using a monitor circuit that tracks the evolution of the circuit performance. In this paper, we propose the use of DC temperature measurements in the proximity of the circuit to perform the monitoring of circuit performance degradation and as an observable variable to adjust the bias of the main devices to restore the degraded performance to the original values.

Metals linked with the most prevalent primary neurodegenerative dementias in the elderly: A narrative review.

The ageing population has been steadily increasing worldwide, leading to a higher risk of cognitive decline and dementia. Environmental toxicants, particularly metals, have been identified as modifiable risk factors for cognitive impairment. Continuous exposure to metals occurs mainly through dietary sources, with older adults being particularly vulnerable.

Plasmonic Titanium Nitride Tubes Decorated with Ru Nanoparticles as Photo-Thermal Catalyst for CO Methanation.

Photo-thermal catalysis has recently emerged as a viable strategy to produce solar fuels or chemicals using sunlight. In particular, nanostructures featuring localized surface plasmon resonance (LSPR) hold great promise as photo-thermal catalysts given their ability to convert light into heat. In this regard, traditional plasmonic materials include gold (Au) or silver (Ag), but in the last years, transition metal nitrides have been proposed as a cost-efficient alternative.

Transition from simple to complex contagion in collective decision-making.

How does the spread of behavior affect consensus-based collective decision-making among animals, humans or swarming robots? In prior research, such propagation of behavior on social networks has been found to exhibit a transition from simple contagion-i.e, based on pairwise interactions-to a complex one-i.e.

Fundamentals and applications of photo-thermal catalysis.

Correction for 'Fundamentals and applications of photo-thermal catalysis' by Diego Mateo , , 2021, , 2173-2210, DOI: 10.1039/D0CS00357C.

Tunable Selectivity in CO Photo-Thermal Reduction by Perovskite-Supported Pd Nanoparticles.

Photo-thermal catalysis has recently emerged as a promising alternative to overcome the limitations of traditional photocatalysis. Despite its potential, most of the photo-thermal systems still lack adequate selectivity patterns and appropriate analysis of the underlying reaction pathways, thus hampering a wide implementation. Herein, a novel photocatalyst based on Pd nanoparticles (NPs) supported on barium titanate (BTO) was prepared for the selective photo-thermal reduction of CO and displayed catalytic rates of up to 8.

An Efficient Metal-Organic Framework-Derived Nickel Catalyst for the Light Driven Methanation of CO.

We report the synthesis of a highly active and stable metal-organic framework derived Ni-based catalyst for the photothermal reduction of CO to CH . Through the controlled pyrolysis of MOF-74 (Ni), the nature of the carbonaceous species and therefore photothermal performance can be tuned. CH production rates of 488 mmol g  h under UV-visible-IR irradiation are achieved when the catalyst is prepared under optimized conditions.

Interplay between mobility, multi-seeding and lockdowns shapes COVID-19 local impact.

Assessing the impact of mobility on epidemic spreading is of crucial importance for understanding the effect of policies like mass quarantines and selective re-openings. While many factors affect disease incidence at a local level, making it more or less homogeneous with respect to other areas, the importance of multi-seeding has often been overlooked. Multi-seeding occurs when several independent (non-clustered) infected individuals arrive at a susceptible population.

Validation, certification and registration of veterinary diagnostic test kits by the World Organisation for Animal Health Secretariat for Registration of Diagnostic Kits.

In the field of diagnostic test validation, World Organisation for Animal Health (OIE) Reference Laboratories (RLs) have a pivotal role and provide the international community with impartial advice and support in the selection, development and validation of diagnostic tests, which can be applied to the specialist diseases for which they are designated. National RLs provide an invaluable function in supporting the introduction, ongoing validation and application of validated diagnostic tests in line with international standards. Experienced staff with extensive knowledge of such systems and access to specialist facilities for conducting work are available to monitor changes or advancements in technology.

Spread of a SARS-CoV-2 variant through Europe in the summer of 2020.

Following its emergence in late 2019, the spread of SARS-CoV-2 has been tracked by phylogenetic analysis of viral genome sequences in unprecedented detail. Although the virus spread globally in early 2020 before borders closed, intercontinental travel has since been greatly reduced. However, travel within Europe resumed in the summer of 2020.

BPF-Based Thermal Sensor Circuit for On-Chip Testing of RF Circuits.

A new sensor topology meant to extract figures of merit of radio-frequency analog integrated circuits (RF-ICs) was experimentally validated. Implemented in a standard 0.35 μm complementary metal-oxide-semiconductor (CMOS) technology, it comprised two blocks: a single metal-oxide-semiconductor (MOS) transistor acting as temperature transducer, which was placed near the circuit to monitor, and an active band-pass filter amplifier.

Fundamentals and applications of photo-thermal catalysis.

Photo-thermal catalysis has recently emerged as an alternative route to drive chemical reactions using light as an energy source. Through the synergistic combination of photo- and thermo-chemical contributions of sunlight, photo-thermal catalysis has the potential to enhance reaction rates and to change selectivity patterns, even under moderate operation conditions. This review provides the fundamentals of localized surface plasmon resonance (LSPR) that explain the photo-thermal effect in plasmonic structures, describes the different mechanistic pathways underlying photo-thermal catalysis, suggests methodologies to disentangle the reaction mechanisms and proposes material design strategies to improve photo-thermal performance.

Emergence and spread of a SARS-CoV-2 variant through Europe in the summer of 2020.

Following its emergence in late 2019, severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) has caused a global pandemic resulting in unprecedented efforts to reduce transmission and develop therapies and vaccines (WHO Emergency Committee, 2020; Zhu et al., 2020). Rapidly generated viral genome sequences have allowed the spread of the virus to be tracked via phylogenetic analysis (Worobey et al.

Genomic analysis of European bovine Staphylococcus aureus from clinical versus subclinical mastitis.

Intramammary infections (IMI) with Staphylococcus aureus are a common cause of bovine mastitis and can result in both clinical (CM) or subclinical mastitis (SCM). Although bacterial isolates of S. aureus differ in their virulence potential it is largely unclear which bacterial virulence factors are responsible for increased clinical severity.

Plasma Exchange: An Effective Rescue Therapy in Critically Ill Patients With Coronavirus Disease 2019 Infection.

Objectives: Infection by severe acute respiratory syndrome coronavirus-2 can induce uncontrolled systemic inflammation and multiple organ failure. The aim of this study was to evaluate if plasma exchange, through the removal of circulating mediators, can be used as rescue therapy in these patients.

Design: Single center case series.

Peripheral venous access devices for apheresis: 16-gauge is not always needed.

Background: Peripheral venous access (PVA) devices for apheresis should be selected to provide enough flow with the least vein damage, but little information is available about PVA devices blood flow rates. The aim of this study was to know the blood flow rates provided by the most frequent PVA devices used in apheresis procedures.

Study Design And Methods: An experimental study was designed to simulate a plasma exchange procedure using citrated whole blood (WB).

Differential Temperature Sensors: Review of Applications in the Test and Characterization of Circuits, Usage and Design Methodology.

Differential temperature sensors can be placed in integrated circuits to extract a signature of the power dissipated by the adjacent circuit blocks built in the same silicon die. This review paper first discusses the singularity that differential temperature sensors provide with respect to other sensor topologies, with circuit monitoring being their main application. The paper focuses on the monitoring of radio-frequency analog circuits.

Long-Term Photostability in Terephthalate Metal-Organic Frameworks.

Prolonged (weeks) UV/Vis irradiation under Ar of UiO-66(Zr), UiO66 Zr-NO , MIL101 Fe, MIL125 Ti-NH , MIL101 Cr and MIL101 Cr(Pt) shows that these MOFs undergo photodecarboxylation of benzenedicarboxylate (BDC) linker in a significant percentage depending on the structure and composition of the material. Routine characterization techniques such as XRD, UV/Vis spectroscopy and TGA fail to detect changes in the material, although porosity and surface area change upon irradiation of powders. In contrast to BCD-containing MOFs, zeolitic imidazolate ZIF-8 does not evolve CO or any other gas upon irradiation.