Evaluation of surfactant-aided polycyclic aromatic hydrocarbon biodegradation by molecular docking and molecular dynamic simulation in the marine environment.

Marine oil spills directly cause polycyclic aromatic hydrocarbons (PAHs) pollution and affect marine organisms due to their toxic property. Chemical and bio-based dispersants composed of surfactants and solvents are considered effective oil spill-treating agents. Dispersants enhance oil biodegradation in the marine environment by rapidly increasing their solubility in the water column.

Synthesis of mono- and bis-spirooxindole derivatives "on water" using double salt of aluminum sulfate-sulfuric acid as a reusable catalyst.

The preparation of double salt of aluminum sulfate-sulfuric acid (Al(SO)·(HSO)·24HO) by the reaction of aluminum sulfate and sulfuric acid in water is described. Aluminum sulfate-sulfuric acid is characterized via some spectroscopic and microscopic techniques such as infrared spectroscopy (IR), X-ray diffraction spectroscopy (XRD), energy-dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) which corroborated the structure of the double salt. This double salt is soluble in water and insoluble in organic solvents.

Synthesis of functionalized dihydro-2-oxopyrroles using graphene oxide as heterogeneous catalyst.

A mild, efficient synthetic approach for the synthesis of highly functionalized dihydro-2-oxopyrroles is developed by using graphene oxide, a readily available and inexpensive material, as an eco-benign solid acid catalyst in ethanol at room temperature. The present methodology displays several advantages such as practical simplicity, high atom economy, easy workup procedure, and high yields of the products.