Reflection-type vapor cell for micro atomic clocks using local anodic bonding of 45° mirrors.

This Letter reports the design, fabrication, and evaluation of reflection-type planar vapor cells for chip-scale atomic clocks. The cell with 2-8 mm cavity length contains two 45° Bragg reflector mirrors assembled using a local anodic bonding. Coherent population trapping resonance of Rb atoms is observed, realizing an atomic clock operation.

Dipole polarizability of alkali-metal (Na, K, Rb)-alkaline-earth-metal (Ca, Sr) polar molecules: prospects for alignment.

Electronic open-shell ground-state properties of selected alkali-metal-alkaline-earth-metal polar molecules are investigated. We determine potential energy curves of the (2)Σ(+) ground state at the coupled-cluster singles and doubles with partial triples (CCSD(T)) level of electron correlation. Calculated spectroscopic constants for the isotopes ((23)Na, (39)K, (85)Rb)-((40)Ca, (88)Sr) are compared with available theoretical and experimental results.

Microwave synthesis from a continuous-wave terahertz oscillator using a photocarrier terahertz frequency comb.

We report low-noise microwave synthesis from radiation with a frequency of 0.3 THz using a photocarrier frequency comb in a photoconductive antenna. The synthesized microwave signal at 1 GHz is phase coherent to the 0.

Ab initio study of ground and excited states of 6Li40Ca and 6Li88Sr molecules.

We present quantum-chemical calculations for the ground and some low-lying excited states of isolated LiCa and LiSr molecules using multi-state complete active space second-order perturbation theory (MS-CASPT2). The potential energy curves (PECs) and their corresponding spectroscopic constants, obtained at the spin-free (SF) and spin-orbit (SO) levels, agree well with available experimental values. Our SO-MS-CASPT2 calculation at the atomic limit (R = 100 a.

Direct comparison of a Ca+ single-ion clock against a Sr lattice clock to verify the absolute frequency measurement.

Optical frequency comparison of the (40)Ca(+) clock transition ν(Ca)((2)S(1/2-)(2D(5/2), 729 nm) against the (87)Sr optical lattice clock transition ν(Sr) ((1)S(0)-(3)P(0), 698 nm) has resulted in a frequency ratio ν(Ca) / ν(Sr) = 0.957 631 202 358 049 9(2 3). The rapid nature of optical comparison allowed the statistical uncertainty of frequency ratio ν(Ca) / ν(Sr) to reach 1 × 10(-15) in 1000s and yielded a value consistent with that calculated from separate absolute frequency measurements of ν(Ca) using the International Atomic Time (TAI) link.