The concerted use of nano-metal particles with catalytic functions and nanoporous materials holds promise for effective air purification and gas sensing; however, only a few studies have used porous glasses as supports for Au nanoparticles. Furthermore, Au/nanoporous glasses with activities comparable to that of Au/TiO, which is a typical Au catalyst, have not been reported to date. This study demonstrates that a nanoporous glass, which is highly acid- and alkali-resistant and chemically stable, can be decorated with Au nanoparticles using an alkali impregnation method.
View Article and Find Full Text PDFTransmittance in porous-glass gas sensors, which use aldol condensation of vanillin and nonanal as the detection mechanism for nonanal, decreases because of the production of carbonates by the sodium hydroxide catalyst. In this study, the reasons for the decrease in transmittance and the measures to overcome this issue were investigated. Alkali-resistant porous glass with nanoscale porosity and light transparency was employed as a reaction field in a nonanal gas sensor using ammonia-catalyzed aldol condensation.
View Article and Find Full Text PDFTo investigate the friction behaviors of elastomer and polyacetal writing tips sliding on various textured glass surfaces, the influences of the pitch size and height of sub-millimeter to millimeter sized texture on friction were examined via reciprocating friction tests. The friction coefficients of each writing tip could be systematically varied by changing the pitch and height of the texture. These changes in friction were based on the relationship between the convex-concave shapes and the contact parts of the writing tip, and hence, influence the adhesive, abrasive, and deformation frictions.
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