Publications by authors named "Masaaki Yamashita"
M-HAT isomerization is a highly reliable method to access thermodynamically stable alkenes with high functional group tolerance. However, synthesis of heteroatom-substituted alkenes by M-HAT isomerization reaction is still underdeveloped. Herein, we report an enamide synthesis using M-HAT via a combination of cobalt and photoredox catalysis.
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- * The researchers developed a new photocatalytic method for DAT deuteration of electron-deficient alkenes that can accommodate various useful functional groups, including haloarenes.
- * This method enables the late-stage deuteration of valuable compounds like deuterated amino acids and donepezil-d, highlighting DAT chemistry as a promising alternative for synthesizing deuterium-containing molecules.