Repeated application of pesticides disturbs microbial communities and cause dysfunctions on soil biological processes. Granstar 75 DF is one of the most used sulfonylurea herbicides on cereal crops; it contains 75% of tribenuron-methyl. Assessing the changes on soil microbiota, particularly on the most abundant bacterial groups, will be a useful approach to determine the impact of Granstar herbicide.
View Article and Find Full Text PDFFreshwater contamination usually comes from runoff water or direct wastewater discharges to the environment. This paper presents a case study which reveals the impact of these types of contamination on the sediment bacterial population. A small stretch of Lerma River Basin, heavily impacted by industrial activities and urban wastewater release, was studied.
View Article and Find Full Text PDFThe borderland of the val de Lièpvre, with lands in Alsace and in the Duchy of Lorraine, and divided by religion and language, offers a rich collection of sources for the history of witchcraft persecution. The territory sharply reveals what was undoubtedly characteristic of witchcraft trials more widely. The crime of witchcraft was considered abominable before the Christian community and God, and its prosecution justified abandoning many of the safeguards and constraints in legal procedure, whether restrictions on the use of torture, the reliance on dubious testimony or even denial of advocacy to the witches.
View Article and Find Full Text PDFThe effect of realistic environmental contamination of diuron on natural epilithic biofilms dwelling bacterial communities and their transformation capacities were investigated by using microcosm experiments. Cobbles carrying biofilms from two sites ("Pau" and "Lacq") located in areas of contrasting pesticide use (urban and agricultural) on the Gave de Pau river (South-West France) were analysed. The water of the upstream site, Pau, was characterised by fewer pesticides than the water of Lacq, whereas concentrations were higher at Pau.
View Article and Find Full Text PDFThe selective activation of different photosensitizers has been carried out under comparable conditions and their efficiency towards di-n-butylsulfide oxidation in oxygenated acetonitrile compared from the product distribution after 150 minutes of irradiation. As expected, the best selectivity towards sulfoxide is obtained with a conventional energy transfer sensitizer such as Rose Bengal (RB), but also with a quinone with a low-lying triplet state, 2,3,5,6-tetrachloro-1,4-benzoquinone (chloranil or CHLO) and with 9,10-dicyanoanthracene (DCA). More significant yields in sulfonic and sulfuric acids are obtained under sensitization with 9,10-anthraquinone (ANT) or a derivative of benzophenone, 4-benzoyl benzoic acid (4-BB), with which additional experiments were carried out in order to discuss the involvement of either singlet oxygen or superoxide radical anion.
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