Background: In this research, a model of factors affecting students' academic success with low socioeconomic status (SES) was explained and evaluated.
Materials And Methods: A mixed-methods research design was used to explain academic success and evaluate it. From this point of view, the research was divided into two parts: grounded theory (GT) and structural equation modeling (SEM).
Objective: Recent studies investigated the role of amino acids (AAs) in weight management. We aimed to determine the association between AAs and three-year change of anthropometric indices and incident obesity.
Materials And Methods: Height, weight, hip, and waist circumference (WC) were collected at baseline and follow up.
The aim of this study was to investigate mediating roles of students' self-system processes and positive academic emotions in a relationship between supporting autonomy and agentic engagement. In This research structural equation modeling was used to analyze a conceptual model. The sample consisted of 452 undergraduate students of Ferdowsi University of Mashhad.
View Article and Find Full Text PDFSilver nanoparticles (NPs) are immobilised on pistachio shell surface by L. leaves extract as an antioxidant media. The Fourier transform infrared spectra, X-ray diffraction, field-emission scanning electron microscopy equipped with energy-dispersive X-ray spectroscopy, and transmission electron microscope analyses confirmed the support of silver NPs on the pistachio shell (Ag NPs/pistachio shell).
View Article and Find Full Text PDFIn this paper, silver nanoparticles (Ag NPs) are synthesized using Achillea millefolium L. extract as reducing and stabilizing agents and peach kernel shell as an environmentally benign support. FT-IR spectroscopy, UV-Vis spectroscopy, X-ray Diffraction (XRD), Field emission scanning electron microscopy (FESEM), Energy Dispersive X-ray Spectroscopy (EDS), Thermo gravimetric-differential thermal analysis (TG-DTA) and Transmission Electron Microscopy (TEM) were used to characterize peach kernel shell, Ag NPs, and Ag NPs/peach kernel shell.
View Article and Find Full Text PDFPalladium nanoparticles (PdNPs) have been immobilized on the surface of walnut shell powder using Equisetum arvense L. leaf extract as reducing and stabilizing agents in this work. FT-IR spectroscopy, UV-Vis spectroscopy, photoluminescence spectroscopy, X-ray diffraction (XRD) pattern, field emission scanning electron microscopy (FESEM), energy dispersive X-ray spectroscopy (EDS), and transmission electron microscopy (TEM) have been used in the characterization of the nanocomposites thus prepared.
View Article and Find Full Text PDFFor the first time the extract of the plant of Salvia hydrangea was used to green synthesis of Pd nanoparticles (NPs) supported on Apricot kernel shell as an environmentally benign support. The Pd NPs/Apricot kernel shell as an effective catalyst was prepared through reduction of Pd ions using Salvia hydrangea extract as the reducing and capping agent and Pd NPs immobilization on Apricot kernel shell surface in the absence of any stabilizer or surfactant. According to FT-IR analysis, the hydroxyl groups of phenolics in Salvia hydrangea extract as bioreductant agents are directly responsible for the reduction of Pd ions and formation of Pd NPs.
View Article and Find Full Text PDFWe report the first detailed study of the characteristics of an octahydro-Schiff base derivative as a new luminophor in the peroxyoxalate chemiluminescence (POCL) system. The effect of reagents on this new POCL system was investigated. In addition, the response surface methodology was used for evaluating the relative significance of variables in this POCL system, establishing models and determining optimal conditions.
View Article and Find Full Text PDFTwo Cu(II) complexes, [Cu₂(μ-atr)(pydc)₂(H₂O)₄]·5H₂O (1) and [Cu(atr)(pydc) (H₂O)]·H₂O (2), with pyridine-2,6-dicarboxylic acid (H₂pydc) and 3-amino-1H-1,2,4-triazole (atr), have been synthesized and characterized. The interaction ability of the both complexes with native calf thymus DNA (CT-DNA) has been monitored as a function of the metal complex-DNA molar ratio. UV-vis spectrophotometry, circular dichroism (CD), thermal denaturation studies, cyclic voltammetry (CV) and viscosity measurements.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
February 2006
1H NMR spectroscopy was used to investigate the stoichiometry and stability of the drug ketamine cation complexes with some crown ethers, such as 15-crown-5 (15C5), aza-15-crown-5 (A15C5), 18-crown-6 (18C6), aza-18-crown-6 (A18C6), diaza-18-crown-6 (DA18C6), dibenzyl-diaza-18-crown-6 (DBzDA18C6) and cryptant [2,2,2] (C222) in acetonitrile (AN), dimethylsulfoxide (DMSO) and methanol (MeOH) at 27 degrees C. In order to evaluate the formation constants of the ketamine cation complexes, the CH3 protons chemical shift (on the nitrogen atom of ketamine) was measured as function of ligand/ketamine mole ratio. The formation constant of resulting complexes were calculated by the computer fitting of chemical shift versus mole ratio data to appropriate equations.
View Article and Find Full Text PDFProton NMR was used as a probe to study the interaction of the Tl(+) ion with 9-18-membered macromonocyclic tri-, tetra-, and hexaamines in dimethylformamide (DMF) solution. A study of proton chemical shift of ligands as a function of Tl(+) ion to ligand mole ratio revealed that the complexation reactions occur in a stepwise manner. Formation of a 1:1 complex is followed by the addition of a second complexant molecule to form a homo-sandwich complex for triazamacrocycle ligands and a mixed ligand complex in the case of hexamethylhexacyclen (HMHCY) and 1,4,7-triazacyclononane ([9]aneN(3)).
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