Emergy-based valuation of glacier ecosystem services: A case from the Tibetan Plateau.

Glaciers provide multiple ecosystem services (ES) to human society. Due to the continued global warming, the valuation of glacier ES is of urgent importance because this knowledge can support the protection of glaciers. However, a systematic valuation of glacier ES is still lacking, particularly from the perspective of ES contributors.

Gold Nanoparticles for Photothermal and Photodynamic Therapy.

Cancer cells exposed to 13 nm gold nanoparticles and irradiated with cw laser light at 532 nm are shown to undergo cell death via two competing causes. When cells contain relatively high quantities of gold nanoparticles and/or receive a high dose of light, photothermal effects dominate, which are independent of the cellular location of the gold nanoparticles and affect all cells in the irradiated area due to the rapid diffusion of heat. In contrast, at lower doses of nanoparticles and light, the photogeneration of singlet oxygen triggers cell death only in cells that contain a sufficient number of nanoparticles.

Effect of Spectral Filtering and Segmental X-ray Tube Current Switch-Off on Interventionalist's Scatter Exposure during CT Fluoroscopy.

Dose optimization in computed tomography (CT) is crucial, especially in CT fluoroscopy (fluoro-CT) used for real-time navigation, affecting both patient and operator safety. This study evaluated the impact of spectral X-ray filtering using a tin filter (Sn filter), and a method called partial-angle computed tomography (PACT), which involves segmentally switching off the X-ray tube current at the ambient dose rate H˙*(10) at the interventional radiologist's (IR) position. Measurements were taken at two body regions (upper body: head/neck; lower body: lower legs/feet) using a 120 kV X-ray tube voltage, 3 × 5.

Technical note: Quantifying radionuclide residues in hospital wastewater: A case study on [I]I and [Lu]Lu/[Lu]Lu.

Background: Historically, [I]I has been a common isotope in radionuclide therapy, with [Lu]Lu-labelled radiopharmaceuticals now seeing a surge in use. These can include no-carrier-added or carrier-added [Lu]Lu with slight impurities of [Lu]Lu with a significantly longer half-life than [I]I. Wastewater from therapy wards can contain a mixture of these radioisotopes.

Agriculture and food security under a changing climate: An underestimated challenge.

Pathways to eradicate global hunger while bending the curve of biodiversity loss unanimously suggest changing to less energy-rich diets, closing yield gaps through agroecological principles, adopting modern breeding technologies to foster stress resilience and yields, as well as minimizing harvest losses and food waste. Against the background of a brief history of global agriculture, we review the available evidence on how the global food system might look given a global temperature increase by 3°. We show that a moderate gain in the area suitable for agriculture is confronted with substantial yield losses through strains on crop physiology, multitrophic interactions, and more frequent extreme events.

A Bayesian Belief Network learning tool integrates multi-scale effects of riparian buffers on stream invertebrates.

Riparian forest buffers have multiple benefits for biodiversity and ecosystem services in both freshwater and terrestrial habitats but are rarely implemented in water ecosystem management, partly reflecting the lack of information on the effectiveness of this measure. In this context, social learning is valuable to inform stakeholders of the efficacy of riparian vegetation in mitigating stream degradation. We aim to develop a Bayesian belief network (BBN) model for application as a learning tool to simulate and assess the reach- and segment-scale effects of riparian vegetation properties and land use on instream invertebrates.

The clam and the dam: A Bayesian belief network approach to environmental flow assessment in a data scarce region.

The Volta clam, Galatea paradoxa, is a freshwater macrobenthic bivalve which is endemic to the Lower Volta River in Ghana. The range of occurrence of the clam has been influenced by the flow regime in the Lower Volta which is in turn controlled by operation of two dams located upstream. Previous research has documented the changes to the Lower Volta due to the dams and attempts have been made to design environmental flows (e-flows), freshwater flows to sustain ecosystems, to inform the re-operation of the dams.

The detection sensitivity of commonly used singlet oxygen probes in aqueous environments.

The sensitivity for singlet oxygen (O) of two convenient O probes, 1,3-diphenylisobenzofuran (DPBF) and 9,10-Anthracenediyl-bis(methylene)dimalonic acid (ABDA), has been investigated in different aqueous environments. Both probes are commercially available at reasonable cost and can be used with standard UV-vis spectrometers. Although DPBF is not soluble in neat water and is not specific to the detection of O, it has very high, essentially diffusion-limited, reactivity towards O; it can trap up to 50% of all O created in alcohol/water or micellar solution, and even more when replacing HO by DO, which makes it highly useful when the process under investigation does not yield much O.

Assessment of Socio-Economic and Climate Change Impacts on Water Resources in Four European Lagoon Catchments.

This study demonstrates the importance of considering potential land use and management changes in climate impact research. By taking into account possible trends of economic development and environmental awareness, we assess effects of global warming on water availability and quality in the catchments of four European lagoons: Ria de Aveiro (Portugal), Mar Menor (Spain), Vistula Lagoon (Poland and Russia), and Tyligulskyi Liman (Ukraine). Different setups of the process-based soil and water integrated model (SWIM), representing one reference and four socio-economic scenarios for each study area: the "business as usual", "crisis", "managed horizons", and "set-aside" scenarios are driven by sets of 15 climate scenarios for a reference (1971-2000) and near future (2011-2040) scenario period.

Developing stakeholder-driven scenarios on land sharing and land sparing - Insights from five European case studies.

Empirical research on land sharing and land sparing has been criticized because preferences of local stakeholders, socio-economic aspects, a bundle of ecosystem services and the local context were only rarely integrated. Using storylines and scenarios is a common approach to include land use drivers and local contexts or to cope with the uncertainties of future developments. The objective of the presented research is to develop comparable participatory regional land use scenarios for the year 2030 reflecting land sharing, land sparing and more intermediate developments across five different European landscapes (Austria, Germany, Switzerland, The Netherlands and Spain).

Periodically poled ridge waveguides in KTP for second harmonic generation in the UV regime.

Waveguide circuits play a key role in modern integrated optics and provide an appealing approach to scalability in quantum optics. We report on periodically poled ridge waveguides in z-cut potassium titanyl phosphate (KTiOPO or KTP), a material that has recently received growing interest due to its unique dispersion properties. Ridges were defined in surface-near rubidium-exchanged KTP by use of a precise diamond-blade dicing saw.

The Art of Scientific Performance.

Humanity builds upon scientific findings, but the credibility of science might be at risk in a 'postfactual' era of advanced information technologies. Here we propose a systemic change for science, to turn away from a growth paradigm and to refocus on quality, characterized by curiosity, surprise, discovery, and societal relevance.

Integrative assessment of climate change for fast-growing urban areas: Measurement and recommendations for future research.

Over the 20th century, urbanization has substantially shaped the surface of Earth. With population rapidly shifting from rural locations towards the cities, urban areas have dramatically expanded on a global scale and represent crystallization points of social, cultural and economic assets and activities. This trend is estimated to persist for the next decades, and particularly the developing countries are expected to face rapid urban growth.

Rb/Ba side-diffused ridge waveguides in KTP.

We report on characterization of ridge waveguides fabricated in KTP (KTiOPO) by use of diamond-blade dicing and Rb/Ba ion exchange. The waveguides were prepared in substrates that have their z-axis in the surface plane, perpendicular to the waveguide direction. This hinders the RbBa ions from diffusion into the depth, as they are only mobile along the z-axis, and improves the waveguide's resistance against elevated temperature.

Sensitive Analysis of Protein Adsorption to Colloidal Gold by Differential Centrifugal Sedimentation.

It is demonstrated that the adsorption of bovine serum albumin (BSA) to aqueous gold colloids can be quantified with molecular resolution by differential centrifugal sedimentation (DCS). This method separates colloidal particles of comparable density by mass. When proteins adsorb to the nanoparticles, both their mass and their effective density change, which strongly affects the sedimentation time.

Characterizing Self-Assembled Monolayers on Gold Nanoparticles.

A key aspect of nanoscience is to control the assembly of complex materials from a "bottom-up" approach. The self-assembly and self-organization of small ligands at the surface of nanoparticles represent a possible starting route for the preparation of (bio)nanomaterials with precise (bio)physical and (bio)chemical properties. However, surface characterization and elucidation of the structure-properties relationship, essential to envisioning such control, remain challenging and are often poorly investigated.

Computational and Experimental Investigation of the Structure of Peptide Monolayers on Gold Nanoparticles.

The self-assembly and self-organization of small molecules on the surface of nanoparticles constitute a potential route toward the preparation of advanced proteinlike nanosystems. However, their structural characterization, critical to the design of bionanomaterials with well-defined biophysical and biochemical properties, remains highly challenging. Here, a computational model for peptide-capped gold nanoparticles (GNPs) is developed using experimentally characterized Cys-Ala-Leu-Asn-Asn (CALNN)- and Cys-Phe-Gly-Ala-Ile-Leu-Ser-Ser (CFGAILSS)-capped GNPs as a benchmark.

Water Quality Is a Poor Predictor of Recreational Hotspots in England.

Maintaining and improving water quality is key to the protection and restoration of aquatic ecosystems, which provide important benefits to society. In Europe, the Water Framework Directive (WFD) defines water quality based on a set of biological, hydro-morphological and chemical targets, and aims to reach good quality conditions in all river bodies by the year 2027. While recently it has been argued that achieving these goals will deliver and enhance ecosystem services, in particular recreational services, there is little empirical evidence demonstrating so.

On the Nexus of the Spatial Dynamics of Global Urbanization and the Age of the City.

A number of concepts exist regarding how urbanization can be described as a process. Understanding this process that affects billions of people and its future development in a spatial manner is imperative to address related issues such as human quality of life. In the focus of spatially explicit studies on urbanization is typically a city, a particular urban region, an agglomeration.

Second harmonic generation of diamond-blade diced KTiOPO ridge waveguides.

We report on the fabrication of ridge waveguides in KTiOPO nonlinear optical crystals through carbon ion irradiation followed by precise diamond blade dicing. The diced side-walls have low roughness, which allows for low propagation loss of ~1dB/cm in fabricated of ridges. The waveguide property investigation has been performed at 1064 nm as well as 532 nm, showing good guidance at both TE and TM polarizations.

Low loss ridge waveguides in lithium niobate thin films by optical grade diamond blade dicing.

We report on the fabrication and characterization of ridge waveguides in lithium niobate thin films by diamond blade dicing. The lithium niobate thin films with a thickness of 1 µm were fabricated by bonding a He-implanted lithium niobate wafer to a SiO(2)-coated lithium niobate wafer and crystal ion slicing. Propagation losses of 1.

Quasi-phase-matched frequency conversion in ridge waveguides fabricated by ion implantation and diamond dicing of MgO:LiNbO(3) crystals.

We report on the fabrication and second harmonic generation from a periodically-poled MgO-doped lithium niobate ridge waveguide within the telecommunication L-band. The ridge waveguide is fabricated by carbon ion implantation and the following diamond blade dicing method. A normalized second harmonic conversion efficiency of 20.

Stabilization of Insulin by Adsorption on a Hydrophobic Silane Self-Assembled Monolayer.

The interaction between many proteins and hydrophobic functionalized surfaces is known to induce β-sheet and amyloid fibril formation. In particular, insulin has served as a model peptide to understand such fibrillation, but the early stages of insulin misfolding and the influence of the surface have not been followed in detail under the acidic conditions relevant to the synthesis and purification of insulin. Here we compare the adsorption of human insulin on a hydrophobic (-CH3-terminated) silane self-assembled monolayer to a hydrophilic (-NH3(+)-terminated) layer.