The range of applications for additive manufacturing is expanding quickly, including mass production of athletic footwear parts, dental ceramics and aerospace components as well as fabrication of microfluidics, medical devices, and artificial organs. The light-induced additive manufacturing techniques used are particularly successful owing to their high spatial and temporal control, but such techniques still share the common motifs of pointwise or layered generation, as do stereolithography, laser powder bed fusion, and continuous liquid interface production and its successors. Volumetric 3D printing is the next step onward from sequential additive manufacturing methods.
View Article and Find Full Text PDFA sub-pixel 16 bit charge coupled device camera featuring superresolution for the soft X-ray regime is presented. Superresolution images (SRIs) are reconstructed from a set of 4 × 4 individual low-resolution images that are recorded for different sub-pixel shifts of the detector. SRIs have a 1.
View Article and Find Full Text PDFOligothiophene-bridged zinc-tin bisporphyrinates were synthesized. Their absorption spectra have been analyzed in terms of exciton interaction and porphyrin-bridge coupling by through-bond interaction and the steady-state fluorescence spectra in terms of differential Stokes shifts for the electron-donating zinc and the electron-accepting tin porphyrinates. Strong quenching of the fluorescence intensity and acceleration of the fluorescence decay as compared to porphyrinate monomers (ZnTPP, SnTPP) were observed.
View Article and Find Full Text PDFThe photophysical properties of the novel hexapyropheophorbide a (P6), and hexakis (pyropheophorbide a)-C60 (FP6) were studied and compared with those of hexakis (pyropheophorbide a)-fullerene [5:1] hexaadduct (FHP6). It was found that after light absorption the pyropheophorbide a molecules in all three compounds undergo very efficient energy transfer as well as partly excitonic interactions. The last process results in the formation of energy traps, which could be resolved experimentally.
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