Dibenzo[a,e]Cyclooctatetraene-Functionalized Polymers as Potential Battery Electrode Materials.

Organic redox polymers are attractive electrode materials for more sustainable rechargeable batteries. To obtain full-organic cells with high operating voltages, redox polymers with low potentials (<2 V versus Li|Li ) are required for the negative electrode. Dibenzo[a,e]cyclooctatetraene (DBCOT) is a promising redox-active group in this respect, since it can be reversibly reduced in a two-electron process at potentials below 1 V versus Li|Li .

Evaluation of Cyclooctatetraene-Based Aliphatic Polymers as Battery Materials: Synthesis, Electrochemical, and Thermal Characterization Supported by DFT Calculations.

Organic electrode materials for rechargeable batteries are becoming a viable alternative for existing technologies. In particular, redox polymers have shown great performances. While many cathode-active derivatives are known, the development of their anode-active counterparts, required for the design of full-organic batteries, lacks behind.

Thianthrene-functionalized polynorbornenes as high-voltage materials for organic cathode-based dual-ion batteries.

Thianthrene-functionalized polynorbornenes were investigated as high-voltage organic cathode materials for dual-ion cells. The polymers show reversible oxidation reactions in solution and as a solid in composite electrodes. Constant current investigations displayed a capacity of up to 66 mA h g(-1) at a high potential of 4.