Unveiling the Crucial Role of Chemical Enhancement in the SERS Analysis of Amphetamine-Metal Interactions on Gold and Silver Surfaces: Importance of Selective Amplification of the Narrow Interval of Vibrational Modes.

The use of addictive substances, including drugs, poses significant health risks and contributes to various social problems, such as increased crime rates associated with substance-induced aggressive behavior. To address these challenges, possession of addictive substances is legally prohibited. However, detecting and analyzing these substances remain a complex task for law enforcement, primarily due to the presence of adulterants or limited sample quantities.

In situ SERS spectroelectrochemical analysis of antioxidants deposited on copper substrates: what is the effect of applied potential on sorption behavior?

The detection of p-coumaric acid and ferulic acid using a combined in situ electrochemical and surface-enhanced Raman scattering spectroscopic technique in specially made electrode cell is described. New in situ spectroelectrochemical cell was designed as the three-electrode arrangement connected via positioning device to fiber-optic probe of Raman spectrometer Dimension P2 (excitation wavelength 785 nm). In situ SERS spectra of p-coumaric acid and ferulic acid were recorded at varying applied negative potentials to copper substrates.