Antiferromagnetic ordering in MnF(salen).

Antiferromagnetic order at [Formula: see text] K has been identified in Mn(III)F(salen), salen  =  H14C16N2O2, an S  =  2 linear-chain system. Using single crystals, specific heat studies performed in magnetic fields up to 9 T revealed the presence of a field-independent cusp at the same temperature where (1)H NMR studies conducted at 42 MHz observed dramatic changes in the spin-lattice relaxation time, T 1, and in the linewidths. Low-field (less than 0.