Phase separation in supramolecular and covalent adaptable networks.

Phase separation phenomena have been studied widely in the field of polymer science, and were recently also reported for dynamic polymer networks (DPNs). The mechanisms of phase separation in dynamic polymer networks are of particular interest as the reversible nature of the network can participate in the structuring of the micro- and macroscale domains. In this review, we highlight the underlying mechanisms of phase separation in dynamic polymer networks, distinguishing between supramolecular polymer networks and covalent adaptable networks (CANs).

Raman Spectroscopy Reveals Phase Separation in Imine-Based Covalent Adaptable Networks.

The introduction of dynamic covalent bonds into cross-linked polymer networks enables the development of strong and tough materials that can still be recycled or repurposed in a sustainable manner. To achieve the full potential of these covalent adaptable networks (CANs), it is essential to understand-and control-the underlying chemistry and physics of the dynamic covalent bonds that undergo bond exchange reactions in the network. In particular, understanding the structure of the network architecture that is assembled dynamically in a CAN is crucial, as exchange processes within this network will dictate the dynamic-mechanical material properties.