Publications by authors named "Marsalek J"

A literature search on traffic related metals in polluted urban snow revealed a significant volume of references representing a substantive knowledge base. The frequently studied metals in urban snow included Zn, Cu, Pb, Cd and Ni. However, comparing metal concentrations across studies proves to be a complex effort due to the variations in site-specific factors among studies, such as traffic intensity, pavement conditions, hydrometeorological conditions, and research method aspects, such as sampling equipment and frequency, and laboratory analytical methods.

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Concentrations of total suspended solids (TSS), trace metals (Cu, Cd, Cr, Zn, Cd, Pb), Na and 16 US EPA priority PAHs in urban snow were studied in the City of Luleå in Northern Sweden. Snow was sampled at six central urban and suburban sites with various traffic intensities, in three sampling surveys (1994-95, 2002-03, 2020-21), repeated for three ages of the urban snow cover of 40, 80, and 120 days, respectively. The older data, from the 1994-95 and 2002-03 surveys, were obtained from the existing literature.

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Building surface materials, exposed to wash-off by rainwater or snowmelt, are recognised as one of the significant urban diffuse pollution sources contributing to the impairment of stormwater quality. The pollution conveyed by roof runoff originates from two potential sources, migration of surface material constituents, or wash-off of pollutants deposited on the surface by atmospheric deposition. This study investigated the releases of metals and several groups of contaminants of emerging concern: alkylphenols, alkylphenol ethoxylates, and phthalates, from commercially available materials, which are commonly used on buildings and structure surfaces in the urban environment.

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Implemented for decades as part of the 'best management practices (BMPs)' for controlling urban runoff impacts on receiving waters, stormwater management ponds (SMPs) have been increasingly viewed as potential habitats for urban wildlife. However, since SMPs are subject to a lot of environmental constraints, research toward assessing their ecological quality and their actual benefits as habitats for biota is needed. In this study, the sediment toxicity of eight SMPs located in Southern Ontario, Canada was assessed using the sediment quality triad (SQT) approach.

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A paired-catchment study of two adjacent commercial areas in northern Sweden, one with Green Infrastructure (GI) storm drainage and the other with a conventional storm sewer system, served to evaluate the hydrological performance of both drainage systems and demonstrate advantages of GI. The GI catchment avoided directly connected impervious areas by diverting runoff from a parking lot to a cascade of three infiltration features, a fractured rock strip draining onto a sloping infiltration area, followed by a collector swale. Both catchments were monitored over 4 years by measuring rainfall, runoff and, in the vicinity of the swale, soil water content and groundwater levels.

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Urban areas play a key role in the production of microplastics (MPs) and their entry into water bodies. This article reviews the literature on the sources, transport, and control of MPs in urban environments with the aim of clarifying the mechanisms underlying these processes. Major MP sources include atmospheric deposition, micro-litter, and tire and road wear particles (TRWPs).

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The microplastics (MP) pollution has been receiving high attention in recent years, because of the massive amounts of plastics it contributes to the environment. Tyre wear and road wear particles (TWP and RWPs) were identified as major sources of MPs, but the observed data on these particles in urban snow deposits and snowmelt is scarce. To contribute to remediation of this situation, a study designed to quantify TWPs and RWPs in urban roadside snowbanks, and assess the MP occurrence in three size fractions, was conducted in the Luleå and Umeå municipalities in Northern Sweden.

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Stormwater and snowmelt runoff is known to contribute to the deterioration of quality of urban surface waters. Vehicular traffic is recognised as a major source of a wide range of pollutants to urban runoff, including conventional pollutants, such as suspended solids and metals, and those referred to as 'contaminants of emerging concern'. The aim of this study was to investigate the contribution of selected metal(loid)s (Cd, Cr, Cu, Ni, Pb, Pd, Sb, W, Zn), polycyclic aromatic hydrocarbons (PAHs), nonylphenols, octylphenols and -ethoxylates, phthalates and bisphenol A (BPA) from vehicular traffic by sampling urban roadside snow at eight sites, with varying traffic intensities, and one control site without direct impacts of traffic.

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Runoff from building and structure surfaces may contribute to the pollution of urban stormwater and, thereby, to the degradation of the receiving water quality. Various micropollutants have been found in surface runoff from buildings in the urban environment, including metals and organic micropollutants. Effective methods for identification of such pollutants and their sources are the prerequisites for the development of control measures.

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Enrichment of soils in three urban drainage swales by metals associated with traffic sources was investigated in a cool temperate climate with seasonal snow. Such swales differed from those not exposed to snow by receiving additional pollutant loads from winter road maintenance involving applications of salt and grit, use of studded tires, and storage and melting of polluted snow cleared from trafficked areas into swales. Among the swales studied, swale L2 in the downtown was the oldest (built around 1960), drained runoff from a road with the highest traffic intensity, and exhibited the highest mean concentrations of most of the metals studied (Pb, Cu, Zn, Cr, Cd, Ni, Co, V, Ti, and W).

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Stormwater sediments of various sizes and densities are recognised as one of the most important stormwater quality parameters that can be conventionally controlled by settling in detention ponds. The bottom grid structure (BGS) is an innovative concept proposed in this study to enhance removal of stormwater sediments entering ponds and reduce sediment resuspension. This concept was studied in a hydraulic scale model with the objective of elucidating the effects of the BGS geometry on stormwater sediment trapping.

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Urban stormwater and snowmelt pollution contributes significantly to the deterioration of surface waters quality in many locations. Consequently, the sources of such pollution have been studied for the past 50 years, with the vehicular transportation sector and the atmospheric deposition identified early as the major pollution sources. In search for mitigation of this pollution, source controls, besides other measures, were recognised as effective pollution mitigation tools, whose successful implementation requires a good knowledge of pollution sources.

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Control of diffuse pollution is critical for achieving good surface water quality status. In this context, pollutant contributions from building materials have received increased attention in recent decades. This study examined the releases of metals, nonylphenols and phthalates from ten common building surface materials (installed in triplicates) into rainwater runoff from six rain events.

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Increasing interest in urban drainage green infrastructure brings attention to grass swales and filter strips (GS&GFS) and their role in stormwater management. While the understanding of the hydrology and hydraulics of these stormwater control measures is adequate for current needs, there are knowledge gaps in understanding the water quality processes in GS&GFS and such a finding motivated preparation of the review paper that follows. The review revealed that most of the empirical studies of GS&GFS flow quality focused on the removal of pollutants associated with road runoff, and particularly solids, with relatively few studies addressing nutrients, traffic associated hydrocarbons, oxygen demanding substances, chloride, and faecal indicator bacteria.

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Inorganic chemicals in urban stormwater and snowmelt runoff originate from catchment geology and anthropogenic activities. The occurrence, partitioning and mobility of six minerals and six trace metal (TM) indicators of anthropogenic activities were studied in stormwater, snowmelt and baseflow in four urban catchments, and the sampling of inorganics was supplemented by measurements of electrical conductivity (EC), pH and total suspended solids (TSSs). Minerals occurred at concentrations several orders of magnitude higher (1-10 mg/L) than those of TMs (10-10 μg/L) and reflected the composition of local groundwater seeping into sewers.

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Implications of three sewer pipe materials (concrete, galvanized corrugated steel, and polyvinyl chloride (PVC)) for stormwater quality were explored in laboratory experiments, in which three types of stormwater, SW1-SW3, were circulated in 0.5 m long sewer pipe sections. SW1 and SW2 represented synthetic rainwater, without and with fine street sediment added (C = 150 mg/L), respectively, and SW3 was actual stormwater with the same sediment addition as SW2.

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Laboratory leaching experiments were performed to study the potential of coarse street sediments (i.e. >250μm) to release dissolved and particulate-bound heavy metals (i.

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The assessment of future trends in urban stormwater quality should be most helpful for ensuring the effectiveness of the existing stormwater quality infrastructure in the future and mitigating the associated impacts on receiving waters. Combined effects of expected changes in climate and socio-economic factors on stormwater quality were examined in two urban test catchments by applying a source-based computer model (WinSLAMM) for TSS and three heavy metals (copper, lead, and zinc) for various future scenarios. Generally, both catchments showed similar responses to the future scenarios and pollutant loads were generally more sensitive to changes in socio-economic factors (i.

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Even in separate sewer systems, wastewater may find its way into the receiving waters through stormwater sewers. The main reasons for this are cross-connections, illicit connections, overflows and leakages through broken sewers. Such discharges may affect receiving water quality and increase risks to public health and aquatic organisms.

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A comparative study of five methods measuring suspended sediment or solid concentrations in water-sediment mixtures indicated that, depending on the method used, broadly varying results can be obtained. For water-sediment mixtures containing sand size particles, the standard TSS method produced negatively biased results, accounting for 0 to 90% of the present solids; the negative bias directly depended on the magnitude of the sand fraction in the water-sediment mixture. The main reason for the differences between the TSS and the rest of the methods laid in the handling of samples; in the former methods, whole samples were analysed, whereas the TSS analysis was performed on sub-samples withdrawn from the water sample, the withdrawal process tending to exclude large particles.

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The effects of climatic changes, progressing urbanization and improved environmental controls on the simulated urban stormwater quality in a northern Sweden community were studied. Future scenarios accounting for those changes were developed and their effects simulated with the Storm Water Management Model (SWMM). It was observed that the simulated stormwater quality was highly sensitive to the scenarios, mimicking progressing urbanization with varying catchment imperviousness and area.

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Ponds that collect and process stormwater have become a prominent feature of urban landscapes, especially in areas recently converted to residential land use in North America. Given their increasing number and their tight hydrological connection to residential catchments, these small aquatic ecosystems could play an important role in urban biogeochemistry. However, some physicochemical aspects of urban ponds remain poorly studied.

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Penicillin G acylase from Achromobacter sp. (NPGA) was studied in the enzymatic synthesis of β-lactam antibiotics by kinetically controlled N-acylation. When compared with penicillin acylase of Escherichia coli (PGA), the NPGA was significantly more efficient at syntheses of ampicillin and amoxicillin (higher S/H ratio and product accumulation) in the whole range of substrate concentrations.

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Stormwater ponds have been widely used to control increased surface runoff resulting from urbanization, and to enhance runoff quality. As receiving waters, they are impacted by intermittent stormwater pollution while also serving as newly created aquatic habitats, which partly offset changes of aquatic ecosystems and their biodiversity by urbanization. Thus, determining ecological risks in stormwater ponds is important for the preservation and rehabilitation of biodiversity in urban areas.

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