Stable Mesoscale Nonwovens of Electrospun Polyacrylonitrile and Interpenetrating Supramolecular 1,3,5-Benzenetrisamide Fibers as Efficient Carriers for Gold Nanoparticles.

The immobilization of metal nanoparticles without agglomeration and leaching within composite nonwovens is often challenging and of great importance, for example, for catalytic applications. In this study, we prepared composite nonwovens based on electrospun polyacrylonitrile (PAN) short fibers and supramolecular terpyridine-functionalized benzene-1,3,5-tricarboxamide () nanofibers by a sheet-forming wet-laid process. The formation of an interpenetrating and entangled network of supramolecular nanofibers and PAN short fibers results in mechanically stable mesoscale nonwovens.