Solvent Role in the Formation of Electric Double Layers with Surface Charge Regulation: A Bystander or a Key Participant?

The charge formation at interfaces involving electrolyte solutions is due to the chemical equilibrium between the surface reactive groups and the potential determining ions in the solution (i.e., charge regulation).

Charge regulation at semiconductor-electrolyte interfaces.

The interface between a semiconductor material and an electrolyte solution has interesting and complex electrostatic properties. Its behavior will depend on the density of mobile charge carriers that are present in both phases as well as on the surface chemistry at the interface through local charge regulation. The latter is driven by chemical equilibria involving the immobile surface groups and the potential determining ions in the electrolyte solution.

Manipulating semiconductor colloidal stability through doping.

The interface between a doped semiconductor material and electrolyte solution is of considerable fundamental interest, and is relevant to systems of practical importance. Both adjacent domains contain mobile charges, which respond to potential variations. This is exploited to design electronic and optoelectronic sensors, and other enabling semiconductor colloidal materials.

The effect of surface charge regulation on conductivity in fluidic nanochannels.

The precise electrostatic potential distribution is very important for the electrokinetic transport in fluidic channels. This is especially valid for small nanochannels where the electric double layers formed at the walls are comparable to the channel width. It can be expected that due to the large surface to volume ratio in such systems, they will exhibit properties that are not detectable in larger channels, capillaries and pores.