The atmosphere is the primary pathway by which mercury enters ecosystems. Despite the importance of atmospheric deposition, concentrations and chemistry of gaseous oxidized (GOM) and particulate-bound (PBM) mercury are poorly characterized. Here, three membranes (cation exchange (CEM), nylon, and poly(tetrafluoroethylene) (PTFE) membranes) were used as a means for quantification of concentrations and identification of the chemistry of GOM and PBM.
View Article and Find Full Text PDFTo advance our understanding of the mercury (Hg) biogeochemical cycle, concentrations and chemistry of gaseous oxidized Hg (GOM), particulate-bound Hg (PBM), and reactive Hg (RM = GOM + PBM) need to be known. The UNR-RMAS 2.0 provides a solution that will advance knowledge.
View Article and Find Full Text PDFArch Environ Contam Toxicol
April 2019
The purpose of this study was to improve our understanding of the relationship between mercury in three species of adult salamanders and relatively pristine first-order streams in western Maryland. We measured the tissue mercury content of 106 northern two-lined salamanders (Eurycea bislineata bislineata), 111 northern dusky (Desmognathus fuscus), and 107 Allegheny mountain dusky (Desmognathus ocrophaeus) salamanders collected during three sampling periods. Averaged over our entire data set, northern two-lined salamanders had significantly greater tissue mercury contents (29.
View Article and Find Full Text PDFArch Environ Contam Toxicol
July 2018
The purpose of this study was to increase our understanding of the bioaccumulation of mercury in northern two-lined salamanders (Eurycea bislineata bislineata) in freshwater stream ecosystems. We collected 111 adults and 131 larval northern two-lined salamanders from six streams in Garrett County, Maryland. These salamanders were collected in April, July, and September 2010.
View Article and Find Full Text PDFEnviron Sci Technol
December 2016
Dry deposition of atmospheric mercury (Hg) to various land covers surrounding 24 sites in North America was estimated for the years 2009 to 2014. Depending on location, multiyear mean annual Hg dry deposition was estimated to range from 5.1 to 23.
View Article and Find Full Text PDFEnviron Sci Technol
December 2015
Coal-fired power plants in the United States are required to reduce their emissions of mercury (Hg) into the atmosphere to lower the exposure of Hg to humans. The effectiveness of power-plant emission controls on the atmospheric concentrations of Hg in the United States is largely unknown because there are few long-term high-quality atmospheric Hg data sets. Here, we present the atmospheric concentrations of Hg and sulfur dioxide (SO2) measured from 2006 to 2015 at a relatively pristine location in western Maryland that is several (>50 km) kilometers downwind of power plants in Ohio, Pennsylvania, and West Virginia.
View Article and Find Full Text PDFEnviron Sci Process Impacts
December 2013
Wet deposition is an important atmospheric mercury (Hg) pathway between air and terrestrial ecosystems. It is measured at numerous locations in the United States (U. S.
View Article and Find Full Text PDFSci Total Environ
March 2012
The purpose of this study was to determine the effects of soil temperature, soil moisture, redox potential (Eh) and soil organic matter (SOM) on the total gaseous mercury (TGM) concentrations in background soils. Our measurements were made in a grass field and deciduous forest at the Piney Reservoir Ambient Air Monitoring Station (PRAAMS) in Garrett County, Maryland. Three plots in each area were sampled every third week from July 2009 to June 2010 at the Oe-A soil horizon interface, the A-E soil horizon interface, and 5 and 10 cm into the E soil horizon.
View Article and Find Full Text PDFThe purpose of this study was to directly measure the dry deposition of gaseous oxidized mercury (GOM) in western Maryland. Annual estimates were made using passive ion-exchange surrogate surfaces and a resistance model. Surrogate surfaces were deployed for seventeen weekly sampling periods between September 2009 and October 2010.
View Article and Find Full Text PDFThe purpose of this study was to determine if wetlands influence mercury concentrations in brook trout (Salvelinus fontinalis), benthic macroinvertebrates, and stream water. On September 26, 2005, water samples, benthic macroinvertebrates, and brook trout were collected from four streams in western Maryland under low-flow conditions. Water samples were also collected in these four streams under high-flow conditions in January 2006.
View Article and Find Full Text PDFWe measured total mercury concentrations in water and fish of Lake Managua and Lake Apoyo. Water mercury concentrations were 10-fold higher in Lake Managua than in Lake Apoyo, although differences in mercury concentration in the most common native fish were not significant. One-fourth of the commercially fished tilapia in Lake Managua exceeded maximum recommended mercury levels for consumption among pregnant women and other at-risk groups, although bioavailability to fishes was lower than in previously studied sites in Brazil and Western Maryland.
View Article and Find Full Text PDFEnviron Sci Technol
August 2002
The purpose of this work was to determine the contribution made by atmospheric nitrogen (N) deposition to the total N input to 10 estuaries on the east coast of the United States. We estimated the amount of N fixed by human activities in the watersheds (N fertilization, biotic N2fixation by legumes and pastures, atmospheric N deposition, and net food and feed import of N) of these 10 estuaries and used a land-use specific approach to estimate the N available for transport to the estuary from different watershed N sources (runoff from agriculture, urban areas and upland forests, point sources, and atmospheric deposition). Total atmospheric N inputs (watershed runoff plus direct deposition to the surface of estuary) accounted for 15-42% of the total N inputs to these 10 estuaries.
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