Porosity-Induced Improvement in KOH Activation of Chitin Nanofiber-Based Porous Carbon Leading to Ultrahigh Specific Capacitance.

The applicability of chitin-based carbon as a supercapacitor electrode material was investigated by adjusting its pore structure through polystyrene latex templating, without significant N doping. 2,2,6,6-tetramethylpiperidinyloxy (TEMPO)-oxidized chitin nanofibers were mixed with polystyrene latex, hydrothermally treated at 220 °C, carbonized, and activated using KOH at 800 °C, yielding activated hierarchical porous carbon. The variation of both polystyrene latex amount and carbonization temperature resulted in changes in the surface area and pore structure, which dictated the degree of pore uniformity and activation efficiency.

Fused sphere carbon monoliths with honeycomb-like porosity from cellulose nanofibers for oil and water separation.

Carbon monoliths with a unique hierarchical surface structure from carbonized cellulose nanofibers were synthesized in pursuit of developing carbon materials from sustainable natural resources. Through a 2-step hydrothermal - carbonization method, TEMPO-oxidized cellulose nanofibers were turned into carbon-rich hydrochar embedded with polystyrene latex as template for 80 nm-sized pores in a honeycomb pattern, while the triblock copolymer Pluronic F-127 was used for a dual purpose not reported before: (1) an interface between the cellulose nanofibers and polystyrene particles, as well as (2) act as a secondary template as ∼1 μm micelles that form hollow carbon spheres. The use of nanofibers allowed more contact between the carbon spheres to coalesce into a working monolith while optimizing the pore structure.