Spatiotemporal Mapping of Efficient Chiral Induction by Helicene-Type Additives in Copolymer Thin Films.

We observed efficient induction of chirality in polyfluorene copolymer thin films by mixing with helicene-type chiral additives based on the dibenzo[c,h]acridine motif. Images obtained from circular dichroism (CD) and circularly polarized luminescence (CPL) microscopy provide information about the chiral arrangements in the thin films with diffraction-limited resolution. The CD signal shows a characteristic dependence on the film thickness, which supports a supramolecular origin of the strong chiral response of the copolymer.

Mapping the broadband circular dichroism of copolymer films with supramolecular chirality in time and space.

Measurements of the electronic circular dichroism (CD) are highly sensitive to the absolute configuration and conformation of chiral molecules and supramolecular assemblies and have therefore found widespread application in the chemical and biological sciences. Here, we demonstrate an approach to simultaneously follow changes in the CD and absorption response of photoexcited systems over the ultraviolet-visible spectral range with 100 fs time resolution. We apply the concept to chiral polyfluorene copolymer thin films and track their electronic relaxation in detail.

Direct Observation of the Exciton Self-Trapping Process in CsCuI Thin Films.

Low-dimensional copper halides, such as CsCuI, have emerged as promising LED materials featuring strongly Stokes-shifted photoluminescence with high quantum yield. Previous calculations suggest an exciton self-trapping mechanism; however, direct experimental evidence for this process is still lacking. Here, we present femtosecond UV-vis transient absorption experiments of CsCuI thin films.

Coherent acoustic phonon dynamics in chiral copolymers.

Coherent phonon oscillations in the UV-Vis transient absorption and circular dichroism response of two chiral polyfluorene-based copolymer thin films are investigated. A slow oscillation in the hundred picosecond regime indicates the propagation of a longitudinal acoustic phonon with a frequency in the gigahertz range through cholesteric films of PFPh and PFBT, which allow for the optical determination of the longitudinal sound velocity in these polymers, with values of (2550 ± 140) and (2490 ± 150) m s, respectively. The oscillation is induced by a strain wave, resulting in a pressure-induced periodic shift of the electronic absorption bands, as extracted from a Fourier analysis of the transient spectra.

Ultrafast Broadband Transient Absorption and Circular Dichroism Reveal Relaxation of a Chiral Copolymer.

We present a study of the photoinduced dynamics of the chiral polyfluorene-phenylene copolymer PFPh in THF and in cholesteric thin films. After photoexcitation at 370 nm in THF, ultraviolet-visible-near-infrared (UV-vis-NIR) transient absorption spectra show fast subpicosecond to picosecond intrachain migration of singlet excitons, solvation dynamics, and an exciton lifetime of 410 ps. The PFPh thin film features also interchain singlet exciton migration and exhibits shorter (2.