Decoupling salt- and polymer-dependent dynamics in polyelectrolyte complex coacervates salt addition.

In polyelectrolyte complex coacervates, changes in salt concentration and changes in polymer concentration are typically strongly coupled, complicating interpretation of the salt- and polymer-concentration-dependent dynamics of these materials. To address this problem, we developed a "salt addition" method for preparation of complex coacervates that allows the salt concentration of a coacervate sample to be varied without changing its polymer concentration. This method was used to prepare coacervates of poly(styrene sulfonate) (PSS) with poly(diallyldimethylammonium chloride) (PDADMAC) with salt concentrations between 1.