Constituents of Calamintha ashei: effects on Florida sandhill species.

Chemical constituents of the perennial shrub Calamintha ashei have been characterized as part of our investigation of the allelopathic properties of this plant. Besides the known monoterpenes, (+)-evodone, (-)-calaminthone and (+)-desacetylcalaminthone, fresh aerial parts of C. ashei provided six new menthofurans, two new germacrane sesquiterpenes, and the six, known flavonoids: 5-desmethoxynobiletin, 5-hydroxy-6,7,8,4'-tetramethoxyflavone, 5,4'-dihydroxy-6,7,8,3'-tetramethoxyflavone, thymonin, 5,4'-dihydroxy-6,7-dimethoxyflavone and 6-hydroxy-7,3'-dimethoxyluteolin.