Structural transitions and magnetic response of supramolecular magnetic polymerlike structures with bidisperse monomers.

Supramolecular magnetic polymerlike (SMP) structures are nanoscaled objects that combine the flexibility of polymeric conformations and controllability of magnetic nanoparticles. The advantage provided by the presence of permanent cross-linkers is that even at high temperature, a condition at which entropy dominates over magnetic interactions, the length and the topology of the SMP structures are preserved. On cooling, however, preexistent bonds constrain thermodynamically equilibrium configurations, making a low-temperature regime for SMP structures worth investigating in detail.