Fabrication of Transparent Pt-TiO Sol and Its Photocatalytic Activity for Hydrogen Evolution.

Titanium dioxide doped with Pt(IV) ions was synthesized via a sol-gel method, incorporating a sol purification process through dialysis. The doped Pt(IV) ions were reduced by UV light irradiation to obtain a transparent Pt-TiO sol, with Pt(0) acting as a cocatalyst for hydrogen evolution. The hydrogen evolution activity of Pt-TiO sol was evaluated under UV light irradiation using methanol as a sacrificial reagent.

MoSe-Sensitized Water Splitting Assisted by C-Dendrons on the Basal Surface.

To facilitate water splitting using MoSe as a light absorber, we fabricated water-dispersible MoSe/C-dendron nanohybrids via physical modification of the basal plane of MoSe. Upon photoirradiation, the mixed-dimension MoSe/C (2D/0D) heterojunction generates a charge-separated state (MoSe⋅/C⋅) through electron extraction from the exciton in MoSe to C. This process is followed by the hydrogen evolution reaction (HER) from water in the presence of a sacrificial donor (1-benzyl-1,4-dihydronicotinamide) and co-catalyst (Pt-PVP).

Group 2 metal bis(arenecarbochalcogenoate)(crown ether) complexes: isolation and structural analysis.

A series of Group 2 metal bis(arenecarbochalcogenoato)(crown ether) complexes M(EE'CAr)2(L)(L')x (M = Mg, Ca, Sr, Ba; Ar = aryl; E = S, Se; E' = O, S; L = H2O or THF; L' = 15-crown-5, 18-crown-6) were synthesized and their structures were revealed by X-ray analyses. The two carbothioato ligands in Mg, Ca and Sr 15-crown-5 complexes are located on the same side of the crown ether plane, while those in Mg, Ca, Sr, and Ba 18-crown-6 compounds are on both sides of the 18-crown-6 plane (trans relative to the plane). For the Ca 15-crown-5 complex, both carbothioato ligands are connected to the central Ca ion through an oxygen atom in a monodentate manner, and the two hydrogen atoms of the coordinated water molecule are intramolecularly hydrogen-bonded with thiocarbonyl sulfur atoms.

Regioselective functionalization at the 7-position of 1,2,3-triphenylbenzo[b]phosphole oxide via P[double bond, length as m-dash]O-directed lithiation.

Various 7-substituted benzo[b]phosphole derivatives were prepared by P[double bond, length as m-dash]O-directed lithiation of 1,2,3-triphenylbenzo[b]phosphole P-oxide and subsequent iodination and cross-coupling reactions. The electron-donating groups introduced at the 7-position produced dramatic solvatofluorochromism owing to the strong charge-transfer character of the excited state of the entire π-system.