A Review on Recent Developments and Prospects for the Oxygen Reduction Reaction on Hollow Pt-alloy Nanoparticles.

Due to their interesting electrocatalytic properties for the oxygen reduction reaction (ORR), hollow Pt-alloy nanoparticles (NPs) supported on high-surface-area carbon attract growing interest. However, the suitable synthesis methods and associated mechanisms of formation, the reasons for their enhanced specific activity for the ORR, and the nature of adequate alloying elements and carbon supports for this type of nanocatalysts remain open questions. This Review aims at shedding light on these topics with a special emphasis on hollow PtNi NPs supported onto Vulcan C (PtNi/C).