Ultra-Small YPO -YAG:Ce Composite Nanophosphors with a Photoluminescence Quantum Yield Exceeding 50.

Synthesis of high quality colloidal Cerium(III) doped yttrium aluminum garnet (Y Al O :Ce , "YAG:Ce") nanoparticles (NPs) meeting simultaneously both ultra-small size and high photoluminescence (PL) performance is challenging, as generally a particle size/PL trade-off has been observed for this type of nanomaterials. The glycothermal route is capable to yield ultra-fine crystalline colloidal YAG:Ce nanoparticles with a particle size as small as 10 nm but with quantum yield (QY) no more than 20%. In this paper, the first ultra-small YPO -YAG:Ce nanocomposite phosphor particles having an exceptional QY-to-size performance with an QY up to 53% while maintaining the particle size ≈10 nm is reported.

Saturation Mechanisms in Common LED Phosphors.

Commercial lighting for ambient and display applications is mostly based on blue light-emitting diodes (LEDs) combined with phosphor materials that convert some of the blue light into green, yellow, orange, and red. Not many phosphor materials can offer stable output under high incident light intensities for thousands of operating hours. Even the most promising LED phosphors saturate in high-power applications, that is, they show decreased light output.

YAG:Ce Phosphor: From Micron-Sized Workhorse for General Lighting to a Bright Future on the Nanoscale.

The renowned yellow phosphor yttrium aluminum garnet (YAG) doped with trivalent cerium has found its way into applications in many forms: as powder of micron sized crystals, as a ceramic, and even as a single crystal. However, additional technological advancement requires providing this material in new form factors, especially in terms of particle size. Where many materials have been developed on the nanoscale with excellent optical properties (e.

Eu Sensitization via Nonradiative Interparticle Energy Transfer Using Inorganic Nanoparticles.

Phosphors have been used successfully for both research and commercial applications for decades. Eu-doped materials are especially promising, because of their extremely stable, efficient, and narrow red emission lines. Although these emission properties are ideal for lighting applications, weak absorption in the blue spectral range has until now prevented the use of Eu-based phosphors in applications based on blue light-emitting diodes.

Nanoscopic control and quantification of enantioselective optical forces.

Circularly polarized light (CPL) exerts a force of different magnitude on left- and right-handed enantiomers, an effect that could be exploited for chiral resolution of chemical compounds as well as controlled assembly of chiral nanostructures. However, enantioselective optical forces are challenging to control and quantify because their magnitude is extremely small (sub-piconewton) and varies in space with sub-micrometre resolution. Here, we report a technique to both strengthen and visualize these forces, using a chiral atomic force microscope probe coupled to a plasmonic optical tweezer.

Controlling magnetic and electric dipole modes in hollow silicon nanocylinders.

We propose a dielectric nanoresonator geometry consisting of hollow dielectric nanocylinders which support geometrical resonances. We fabricate such hollow Si particles with an outer diameter of 108-251 nm on a Si substrate, and determine their resonant modes with cathodo-luminescence (CL) spectroscopy and optical dark-field (DF) scattering measurements. The scattering behavior is numerically investigated in a systematic fashion as a function of wavelength and particle geometry.

Ubiquity of optical activity in planar metamaterial scatterers.

Recently it was discovered that periodic lattices of metamaterial scatterers show optical activity, even if the scatterers or lattice show no 2D or 3D chirality, if the illumination breaks symmetry. We demonstrate that such "pseudochirality" is intrinsic to any single planar metamaterial scatterer and in fact has a well-defined value at a universal bound. We argue that in any circuit model, a nonzero electric and magnetic polarizability derived from a single resonance automatically imply strong bi-anisotropy, i.