Compositional boundary layers trigger liquid unmixing in a basaltic crystal mush.

The separation of immiscible liquids has significant implications for magma evolution and the formation of magmatic ore deposits. We combine high-resolution imaging and electron probe microanalysis with the first use of atom probe tomography on tholeiitic basaltic glass from Hawaii, the Snake River Plain, and Iceland, to investigate the onset of unmixing of basaltic liquids into Fe-rich and Si-rich conjugates. We examine the relationships between unmixing and crystal growth, and the evolution of a nanoemulsion in a crystal mush.

Architecture and dynamics of magma reservoirs.

This introductory article provides a synopsis of our current understanding of the form and dynamics of magma reservoirs in the crust. This knowledge is based on a range of experimental, observational and theoretical approaches, some of which are multidisclipinary and pioneering. We introduce and provide a contextual background for the papers in this issue, which cover a wide range of topics, encompassing magma storage, transport, behaviour and rheology, as well as the timescales on which magma reservoirs operate.

Magma chambers versus mush zones: constraining the architecture of sub-volcanic plumbing systems from microstructural analysis of crystalline enclaves.

There are clear microstructural differences between mafic plutonic rocks that formed in a dynamic liquid-rich environment, in which crystals can be moved and re-arranged by magmatic currents, and those in which crystal nucleation and growth are essentially in situ and static. Crystalline enclaves, derived from deep crustal mushy zones and erupted in many volcanic settings, afford a unique opportunity to use the understanding of microstructural development, established from the study of intrusive plutons, to place constraints on the architecture of sub-volcanic systems. Here, we review the relevant microstructural literature, before applying these techniques to interrogate the crystallization environments of enclaves from the Kameni Islands of Santorini and Rábida Volcano in the Galápagos.

Melt segregation from silicic crystal mushes: a critical appraisal of possible mechanisms and their microstructural record.

One of the outstanding problems in understanding the behavior of intermediate-to-silicic magmatic systems is the mechanism(s) by which large volumes of crystal-poor rhyolite can be extracted from crystal-rich mushy storage zones in the mid-deep crust. The mechanisms commonly invoked are hindered settling, micro-settling, and compaction. The concept of micro-settling involves extraction of grains from a crystal framework during Ostwald ripening and has been shown to be non-viable in the metallic systems for which it was originally proposed.

Microstructural evidence for crystallization regimes in mafic intrusions: a case study from the Little Minch Sill Complex, Scotland.

The magma forming the 20 m thick crinanitic/picrodoleritic Dun Raisburgh sill, part of the Little Minch Sill Complex of NW Scotland, comprised a mafic carrier liquid with a crystal cargo of plagioclase and olivine (1 vol%). The olivine component of the cargo settled on the floor of the intrusion while the more buoyant plagioclase component remained suspended during solidification, resulting in a relatively high plagioclase content in the centre of the sill. The settled olivine grains form a lower fining-upwards sequence overlain by a poorly sorted accumulation formed of grains that grew within the convecting magma.

Crystal settling and convection in the Shiant Isles Main Sill.

The 168 m-thick Shiant Isles Main Sill is a composite body, dominated by an early, 24 m-thick, picrite sill formed by the intrusion of a highly olivine-phyric magma, and a later 135 m-thick intrusion of olivine-phyric magma that split the earlier picrite into a 22 m-thick lower part and a 2 m-thick upper part, forming the picrodolerite/crinanite unit (PCU). The high crystal load in the early picrite prevented effective settling of the olivine crystals, which retain their initial stratigraphic distribution. In contrast, the position of the most evolved rocks of the PCU at a level ~80% of its total height point to significant accumulation of crystals on the floor, as evident by the high olivine mode at the base of the PCU.

The thickness of the crystal mush on the floor of the Bushveld magma chamber.

The thickness of the crystal mush on magma chamber floors can be constrained using the offset between the step-change in the median value of dihedral angles formed at the junctions between two grains of plagioclase and a grain of another phase (typically clinopyroxene, but also orthopyroxene and olivine) and the first appearance or disappearance of the liquidus phase associated with the step-change in median dihedral angle. We determined the mush thickness in the Rustenburg Layered Suite of the Bushveld Complex at clinopyroxene-in (in Lower Main Zone) and magnetite-in (in Upper Zone). We also examined an intermittent appearance of cumulus apatite in Upper Zone, using both the appearance and disappearance of cumulus apatite.