Publications by authors named "Maria Tsagkaraki"

Article Synopsis
  • This study highlights the health risks associated with oxygenated polycyclic aromatic hydrocarbons (OPAHs) and their need for monitoring alongside traditional PAHs to evaluate urban health impacts.
  • An extensive sampling campaign in Athens, Greece, revealed seasonal variations in polycyclic aromatic compounds (PACs), primarily influenced by residential wood burning, especially during winter.
  • The impact of external factors like biomass burning and the COVID-19 lockdown on PAC levels was significant, emphasizing the importance of regulating biomass burning to improve urban air quality.
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This work evaluates the aerosol oxidative potential (OP) and its changes from modified air pollution emissions during the COVID-19 lockdown period in 2020, with the intent of elucidating the contribution of aerosol sources and related components to aerosol OP. For this, daily particulate matter (PM) samples at an urban background site were collected and analyzed with a chemical (acellular) assay based on Dithiothreitol (DTT) during the COVID-19 restriction period in Athens (Greece). The obtained time-series of OP, PM, organic matter (OM) and SO of the pre-, post- and lockdown periods were also compared to the data of the same time periods during the years 2017-2019.

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The importance of dust and biomass burning episodes on the atmospheric concentration of water-soluble reactive phosphate (SRP) was determined in the eastern Mediterranean. SRP was measured with a new rapid real-time automated analytical system with a time resolution of a few minutes per sample and with an extremely low detection limit. The average atmospheric concentration of SRP during the sampling campaign was estimated at 0.

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The composition of atmospheric aerosols is dynamic and influenced by their emission sources, organic and inorganic composition, transport pathways, chemical and physical processes, microorganisms' content and more. Characterization of such factors can improve the ability to evaluate air quality and health risks under different atmospheric scenarios. Here we investigate the microbial composition of the atmospheric particulate matter (<10 μm; PM), sampled in Bolu, Turkey, and the linkage to the chemical composition changes, and different environmental factors.

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Oxidative potential (OP), which is the ability of certain components in atmospheric particles to generate reactive oxidative species (ROS) and deplete antioxidants in vivo, is a prevailing toxicological mechanism underlying the adverse health effects associated with exposure to ambient aerosols. While previous studies have identified the high OP of fresh biomass burning organic aerosols (BBOA), it remains unclear how it evolves throughout atmospheric transport. Using the dithiothreitol (DTT) assay as a measure of OP, a combination of field observations and laboratory experiments is used to determine how atmospheric aging transforms the intrinsic OP (OP) of BBOA.

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