7-Pyridylindoles: synthesis, structure, and properties.

A series of three isomeric 7-pyridylindoles (7-PIs) are prepared where the pyridine attachment is through C2, C3, or C4. These systems are prepared by a combination of the Bartoli reaction and the Stille coupling with an appropriate pyridyl stannane. By treatment with CH(3)I, the 7-PIs can be converted to their pyridinium salts.