Asymmetric Membranes Obtained from Sulfonated HIPS Waste with Potential Application in Wastewater Treatment.

The recovery and reuse of high-impact polystyrene (HIPS) into high-value products is crucial for reducing environmental thermoplastics waste and promoting sustainable materials for various applications. In this study, asymmetric membranes obtained from sulfonated HIPS waste were used for salt and dye removals. The incorporation of sulfonic acid (-SOH) groups into HIPS waste by direct chemical sulfonation with chlorosulfonic acid (CSA), at two different concentrations, was investigated to impart antifouling properties in membranes for water treatment.

Tailoring membrane technology with galactomannan for enhanced biocompatibility and antibacterial action.

In this study, we elaborated advanced asymmetric membranes using polyvinyl alcohol (PVA) and a galactomannan (GA) derived from Delonix regia seeds, a blend known for its biocompatibility properties. These membranes, crosslinked with sulfosuccinic acid (SSA), exhibited remarkable enhancements in various crucial aspects for biomedical applications, in particular provides antibacterial properties. The incorporation of GA leads to the formation of globular regions, enhancing crosslinking and swelling properties.

Synthesis Characterization and Physicochemical Properties of Rigid Alicyclic Polyimide Films Based on Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic Dianhydride.

Four polyimides based on bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic dianhydride (BTD), , and , with different rigid substituted diamines were synthesized.

Preparation and Characterization of Strongly Sulfonated Acid Block and Random Copolymer Membranes for Acetic Acid Esterification with 2-Propanol.

In this paper, we report the synthesis of block and random copolymers of 2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS) and methyl methacrylate (MMA), with different AMPS feed ratios. These solution-processable copolymers with strongly sulfonated acid groups resulted in membranes with tunable ion exchange (IEC) and water absorption capacities. AFM images confirmed the microphase separation of block copolymer membrane, annealed under the appropriate conditions.

Synthesis of Poly(2-Acrylamido-2-Methylpropane Sulfonic Acid) and its Block Copolymers with Methyl Methacrylate and 2-Hydroxyethyl Methacrylate by Quasiliving Radical Polymerization Catalyzed by a Cyclometalated Ruthenium(II) Complex.

The first example of quasiliving radical polymerization and copolymerization of 2-acrylamido-2-methylpropane sulfonic acid (AMPS) without previous protection of its strong acid groups catalyzed by [Ru(-CH-2-py)(phen)(MeCN)]PF complex is reported. Nuclear magnetic resonance (RMN) and gel permeation chromatography (GPC) confirmed the diblock structure of the sulfonated copolymers. The poly(2-acryloamido-2-methylpropanesulfonic acid)--poly(methyl methacrylate) (PAMPS--PMMA) and poly(2-acryloamido-2-methylpropanesulfonic acid)--poly(2-hydroxyethylmethacrylate) (PAMPS--PHEMA) copolymers obtained are highly soluble in organic solvents and present good film-forming ability.

Design, Synthesis and Biological Evaluation of 2-(2-Amino-5(6)-nitro-1H-benzimidazol-1-yl)-N-arylacetamides as Antiprotozoal Agents.

Parasitic diseases are a public health problem affecting millions of people worldwide. One of the scaffolds used in several drugs for the treatment of parasitic diseases is the benzimidazole moiety, a heterocyclic aromatic compound. This compound is a crucial pharmacophore group and is considered a privileged structure in medicinal chemistry.