Publications by authors named "Maria Koifman Khristosov"

Article Synopsis
  • - The study explores the use of crystallographic defects, particularly twin boundaries, in gold (Au) substrates to enhance the growth of semiconductor nanocrystals like gold(I)-cyanide (AuCN), which have various applications.
  • - It discusses how twin boundaries create ledges that expose new crystal facets, facilitating the directed growth of AuCN on these surfaces in specific orientations.
  • - The findings suggest that controlling this growth could lead to nanoscale patterning of semiconductors, allowing adjustments to their properties, especially the band gap, which is crucial for electronic and optical applications.
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Dislocations in metals affect their properties on the macro- and the microscales. For example, they increase a metal's hardness and strength. Dislocation outcrops exist on the surfaces of such metals, and atoms in the proximity of these outcrops are more loosely bonded, facilitating local chemical corrosion and reactivity.

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Nanoporous gold is widely used in research and nanotechnology because of its diverse properties, including high surface area and catalytic activity. The ligament size is usually considered as one of the main parameters controlling thermal stability and mechanical properties of nanoporous gold. Recently we developed a method for creating nanoporous single crystal gold particles using eutectic decomposition of Au-Ge, followed by selective etching of Ge.

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Single crystals in nature often demonstrate fascinating intricate porous morphologies rather than classical faceted surfaces. We attempt to grow such crystals, drawing inspiration from biogenic porous single crystals. Here we show that nanoporous single crystals of gold can be grown with no need for any elaborate fabrication steps.

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Crystals in nature often demonstrate curved morphologies rather than classical faceted surfaces. Inspired by biogenic curved single crystals, we demonstrate that gold single crystals exhibiting curved surfaces can be grown with no need of any fabrication steps. These single crystals grow from the confined volume of a droplet of a eutectic composition melt that forms via the dewetting of nanometric thin films.

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