Single flow-based system for the automatic multiparametric nutrients (NPK & Fe) assessment in soil leachates.

A multiparametric sequential injection system for the determination of phosphate, nitrite, nitrate, potassium, and iron(III) in a single manifold was developed. The main goal of the proposed method was to develop an efficient tool to assess a number of essential chemical compounds in soils, providing the corresponding information on soil fertility and, additionally, information on possible groundwater contamination. The method was applied for the quantification of the aforementioned parameters in simulated leachates produced in laboratory-scale core columns.

Sequential injection method for bi-parametric determination of iron and manganese in soil leachates.

The aim of this work was to develop a sequential injection (SI) method for the determination of the micronutrients iron and manganese, in soil leachates, as a tool to assess potential groundwater contamination. The described sequential injection method was based on the reaction of iron with chelator MRB12, a greener alternative chromogenic reagent, and the reaction of manganese with zincon, within a single manifold. The developed SI method enabled the determination of iron in the range 0.