Ring-opening polymerization of emulsion-templated deep eutectic system monomer for macroporous polyesters with controlled degradability.

Biodegradable polyesters with interconnected macroporosity, such as poly(l-lactide) (PLLA) and poly(ε-caprolactone) (PCL), have gained significant importance in the fields of tissue engineering and separation. This study introduces functional macroinitiators, specifically polycaprolactone triol (PCL) and polyethylene glycol (PEG), both OH-terminated, in the solventless ring-opening polymerization (ROP) of a liquid deep eutectic system monomer (DESm) composed of LLA and CL at a 30 : 70 molar ratio, respectively. The macroinitiators selectively initiate the organocatalyzed ROP of LLA in the DESm during the first polymerization stage, thereby modifying the PLLA architecture.

Polydimethylsiloxane nanocomposite macroporous films prepared Pickering high internal phase emulsions as effective dielectrics for enhancing the performance of triboelectric nanogenerators.

Polydimethylsiloxane (PDMS) nanocomposite (NC) macroporous films were prepared by a Pickering high internal phase emulsion (HIPE) templating technique and used as effective dielectrics for enhancing the performance of triboelectric-nanogenerators (TENGs). HIPEs were formulated using commercial PDMS and water as the continuous and dispersed phase, respectively. The formation and solidification of PDMS-based HIPEs were possible through stabilization with silver-nanoparticles (Ag-Nps) and surfactant (Span 20) mixtures.