Waste Symbiosis through the Synthesis of Highly Crystalline LTA and SOD Zeolites.

In recent years, the demand for natural and synthetic zeolites has surged due to their distinctive properties and myriad industrial applications. This research aims to synthesise crystalline zeolites by co-recycling two industrial wastes: salt slag (SS) and rice husk ash (RHA). Salt slag, a problematic by-product of secondary aluminium smelting, is classified as hazardous waste due to its reactive and leachable nature, though it is rich in aluminium.

Use of a Waste-Derived Linde Type-A Immobilized in Agarose for the Remediation of Water Impacted by Coal Acid Mine Drainage at Pilot Scale.

A new adsorbent based on an immobilized waste-derived LTA zeolite in agarose (AG) has proven to be an innovative and efficient alternative for removing metallic contaminants from water impacted by acid mine drainage (AMD) because the immobilization prevents the solubilization of the zeolite in acidic media and eases its separation from the adsorbed solution. A pilot device was developed containing slices of the sorbent material [AG (1.5%)-LTA (8%)] to be used in a treatment system under an upward continuous flow.

Highly efficient removal of aluminum, iron, and manganese ions using Linde type-A zeolite obtained from hazardous waste.

Coal acid mine drainage (AMD) contaminates natural water to form mine-impacted water (MIW), which is characterized by high levels of acidity, sulfate, and metallic ions. This study investigates the use of a Linde Type-A (LTA) zeolite obtained from a hazardous industrial waste for Al, Fe, and Mn removal from synthetic aqueous solutions. The aim of this study is to stablish a basis for the subsequent treatment of MIW in order to obtain reuse water.

Evaluating the effect of air flow rate on hybrid and conventional membrane bioreactors: Implications on performance, microbial activity and membrane fouling.

This study addressed the impact of air flow rate on the performance, membrane fouling behaviour and microbial community of a sequencing batch conventional membrane bioreactor (SB-MBR) and a sequencing batch hybrid membrane bioreactor (SB-HMBR) with carrier media for biofilm growth. Two different scenarios were evaluated: high (6.4 L min) and low (1.

Biostimulation of sulfate-reducing bacteria and metallic ions removal from coal mine-impacted water (MIW) using shrimp shell as treatment agent.

This paper comprises several assays aiming to identify the basis for the bioremediation of mine-impacted water (MIW). To do so, the conditions for build anoxic microcosms for treating this effluent were varied, containing MIW, and a source of chitin, to biostimulate sulfate-reducing bacteria (SRB). The chitin sources were: commercial chitin (CHIT) and shrimp shell (SS), which in addition to chitin, contains CaCO, and proteins in its composition.

Sulfate removal from mine-impacted water by electrocoagulation: statistical study, factorial design, and kinetics.

This work aimed to remove sulfate and acidity from mine-impacted water (MIW) via electrocoagulation (EC), a technique which stands as an advanced alternative to chemical coagulation in pollutant removal from wastewaters. The multiple electrochemical reactions occurring in the aluminum anode and the stainless steel cathode surfaces can form unstable flakes of metal hydroxysulfate complexes, causing coagulation, flocculation, and floatation; or, adsorption of sulfate on sorbents originated from the electrochemical process can occur, depending on pH value. Batch experiments in the continuous mode of exposition using different current densities (35, 50, and 65 A m) were tested, and a statistical difference between their sulfate removals was detected.

Chitin as a substrate for the biostimulation of sulfate-reducing bacteria in the treatment of mine-impacted water (MIW).

This study aims to know the basis of sulfate-reducing bacteria (SRB) and chitin source relationship for the development of a biotreatment system for mine-impacted water (MIW). The MIW consists of river water impacted by coal acid mine drainage (AMD), an extremely acid effluent, rich in sulfate and dissolved metal ions, with a high pollutant potential. Chitin was used as metal ion sorbent and biostimulant of SRB, whose anaerobic dissimilatory metabolism reduces sulfate to sulfide.

Comparative study on treatment performance, membrane fouling, and microbial community profile between conventional and hybrid sequencing batch membrane bioreactors for municipal wastewater treatment.

A sequencing batch conventional membrane bioreactor (SB-CMBR) and sequencing batch hybrid membrane bioreactor (SB-HMBR) were operated in parallel under two different hydraulic retention times (HRTs) (namely 12 h and 6 h), and their chemical oxygen demand (COD) and nutrient removal performance, membrane fouling behavior, and microbial community characteristics were compared. Both systems exhibited high organic matter (> 95%) and ammonium (> 98%) removal performance regardless of the HRT applied. As the HRT was reduced from 12 to 6 h, total nitrogen removal slightly increased in both reactors, being higher in the carrier-based MBR, where anoxic zones may have been established within the biofilm.

Aplication of the statistical experimental design to optimize mine-impacted water (MIW) remediation using shrimp-shell.

Mine-impacted water (MIW) is one of the most serious mining problems and has a high negative impact on water resources and aquatic life. The main characteristics of MIW are a low pH (between 2 and 4) and high concentrations of SO and metal ions (Cd, Cu, Ni, Pb, Zn, Fe, Al, Cr, Mn, Mg, etc.), many of which are toxic to ecosystems and human life.

Aqueous and solid complexes of iron(III) with hyaluronic acid. Potentiometric titrations and infrared spectroscopy studies.

The coordination of iron(III) ion to hyaluronic acid (Hyal) in aqueous solutions and solid state was accomplished by potentiometric titrations and infrared spectroscopy. The potentiometric titration studies provided the binding constants for the complexes found in the systems and the speciation of these species according to the variation of pH values. The complexes found presented a complexing ability through both the chelating moieties of Hyal (via the N-glucosamine and D-glucoronic acid), showing no special preference for either one while in solid state, but when in aqueous solution the complexation via the N-glucosamine moiety was the preferred, forming two complexed species, ML and ML(2) (log K(ML)=8.