Publications by authors named "Margherita Silvetti"

In this study we evaluated the microbiological and biochemical impact of iron-based water treatment residuals (Fe-WTRs) and municipal solid waste compost (MSWC), alone and combined, on three different soils co-contaminated with arsenic (As) and trace-metals (TM), i.e. Pb, Cu and Zn.

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The ability of two municipal solid waste composts (MSW-Cs) to sorb antimony(V) in acidic conditions (pH 4.5) was investigated. Sorption isotherms and kinetics showed that both MSW-Cs could sorb antimony(V), even if in different amounts (~ 0.

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In this study we report on the interactions between the water-soluble fraction (WSF) of two municipal solid waste composts (C1- and C2-WSF) with Pb(II) and Cu(II) ions at pH 4.5. The Me(II) addition to the compost-WSFs led to the formation of soluble Me(II)-organic complexes (as highlighted by FT-IR spectroscopy), and to a decrease of the trace metals' solubility, which was greater for Pb(II) than Cu(II).

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The ability of two municipal solid waste composts (MSW-C) to sorb As(V) in the presence of Pb(II) and in acidic conditions was investigated. Sorption isotherms and kinetics showed that both MSW-C were able to sorb As(V) in a similar way (∼0.24mmolg MSW-C), but only when Pb(II) was present (0.

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In this study, we investigated the ability of Fe- and Al-based water treatment residues (Fe- and Al-WTR) to accumulate Pb(II) and Cu(II) at pH 4.5. The role of the inorganic and organic fractions of WTRs in metals sorption was also assessed.

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Article Synopsis
  • Four iron and aluminum-based products were tested for stabilizing arsenic (As) and heavy metals in contaminated soil, including red mud (RM), hematite, iron-rich water treatment residual (Fe-WTR), and amorphous aluminum hydroxide (Al-OH).
  • After 6 months, all treatments lowered labile As levels, with Al-OH also reducing water-soluble heavy metals, while RM increased soil microbial activity despite inhibiting bean germination.
  • Al-OH showed the best overall results by promoting microbial growth and increasing plant growth, making it a strong candidate for future soil remediation efforts, while RM's effectiveness in such scenarios may need reevaluation.
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  • A study was conducted to evaluate the effectiveness of two water treatment residues, Fe-based (Fe-WTR) and Al-based (Al-WTR), in removing arsenate and phosphate from water at different pH levels (4.0, 7.0, and 9.0).
  • Results showed that Fe-WTR had a higher capacity for sorbing both anions, especially at pH 4.0, attributed to its greater manganese content that helps form manganese-phosphate precipitates.
  • The sorption mechanism largely involves the formation of inner-sphere surface complexes, supported by FT-IR spectroscopy indicating specific bonding vibrations for arsenate and phosphate.
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  • * Citrate was found to be more effective than malate in mobilizing As, with higher amounts released from the RM soil compared to the untreated soil.
  • * The results suggest that two key mechanisms—competition for adsorption sites and dissolution of Fe/Al oxi-hydroxides—contribute to the increased solubility of arsenic when treated with these organic acids.
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In this study we evaluated the efficiency of red muds (RM, a bauxite residue) to immobilize the arsenic present in a polluted sub-acidic soil (UP-soil; total As 2428 mg kg(-1)) and to influence some chemical, biochemical and microbiological properties after 2 years since RM addition. The RM addition caused a pH increase, a striking decrease of total organic carbon and a significant increase of water-soluble C, N and P. The analysis of As mobility through sequential extraction showed a reduction of the water-soluble arsenic in the RM-soil compared to the UP-soil (3.

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In the present work we investigated the interactions established between red mud (RM) and phosphate anions (P) at pH 4.0, 7.0 and 10.

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In this study we evaluated the arsenate adsorption capacity of red muds (RM), wastes tailing from the alumina production, at different pH values (4, 7, and 10). RM samples were artificially enriched in batch tests with solutions containing increasing concentrations of As(V). The pH of the solution significantly affected the adsorption, which increased with the decrease of pH.

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