Dielectric switching in correlation with the structural phase transitions in tetrapropylammonium perchlorate.

The crystals of the tetrapropylammonium perchlorate ([(CHCHCH)N]ClO, TePrAClO) compound undergo two reversible phase transitions: at = 284 K and at = 445 K. The observed phase transitions and distinct dielectric and relaxation effects are due to the dynamic motions of the organic cations and anionic framework. The crystals become ordered at low temperatures, then disordered at room temperature (propyl chains of the organic part as well as perchlorate ions are disordered over the mirror plane at = 1/4 and 3/4) and highly disordered at high temperatures.

High-fidelity all-fiber amplification of a gain-switched laser diode.

We demonstrate a multistage erbium fiber amplifier seeded by a gain-switched laser diode operating at a wavelength of 1550 nm and a repetition rate of 1 MHz. The pulse energy is 0.5 μJ, and the pulse duration is 40 ps, resulting in a peak power of 11.

Spectroscopy and calculations for 4f(N) → 4f(N-1)5d transitions of lanthanide ions in K3YF6.

In the present work, we report on the combined experimental and theoretical studies of the 4f-5d spectra of Ce(3+), Pr(3+), Nd(3+), Eu(3+), Gd(3+), Tb(3+), Dy(3+), and Er(3+) ions in a newly synthesized K3YF6 matrix. The low temperature experimental 4f-5d excitation spectra have been analyzed and compared with the results of the energy-level and intensity calculations. For this theoretical analysis, the extended phenomenological crystal-field model for the 4f(N-1)5d configuration (i.

NaYF4:Pr3+ nanocrystals displaying photon cascade emission.

The quantum-cutting process is observed in nanocrystalline fluoride (NaYF(4)) doped with Pr(3+). The thermal decomposition synthesis method was used to synthesize the NaYF(4) nanocrystals with an average size of 42 nm. The morphological high resolution transmission electron microscopy (HRTEM), structural X-ray diffraction (XRD) and spectroscopy, with the use of synchrotron radiation, have been employed to characterize the material.

Unusual behavior of Tb3+ in K3YF6 green-emitting phosphor.

We report on photoluminescence studies of Tb3+ in a polycrystalline cryolite type K3YF6 host. The location of the Tb3+ in the center of inversion forbids the electric-dipole transitions of terbium ions in this material. As a consequence almost the entire luminescence intensity is related to the 5D4-(7)F5 magnetic-dipole transition, and it is contained in the extremely narrow spectral bandwidth amounting to 1.