Performance of optimal linear-response processes in driven Brownian motion far from equilibrium.

Considering the paradigmatic driven Brownian motion, we perform extensive numerical analysis on the performance of optimal linear-response processes far from equilibrium. We focus on the overdamped regime where exact optimal processes are known analytically and most experiments operate. This allows us to compare the optimal processes obtained in linear response and address their relevance to experiments using realistic parameter values from experiments with optical tweezers.

Shortcuts to Thermodynamic Quasistaticity.

The operation of near-term quantum technologies requires the development of feasible, implementable, and robust strategies of controlling complex many body systems. To this end, a variety of techniques, so-called "shortcuts to adiabaticity," have been developed. Many of these shortcuts have already been demonstrated to be powerful and implementable in distinct scenarios.

Kibble-Zurek Scaling from Linear Response Theory.

While quantum phase transitions share many characteristics with thermodynamic phase transitions, they are also markedly different as they occur at zero temperature. Hence, it is not immediately clear whether tools and frameworks that capture the properties of thermodynamic phase transitions also apply in the quantum case. Concerning the crossing of thermodynamic critical points and describing its non-equilibrium dynamics, the Kibble-Zurek mechanism and linear response theory have been demonstrated to be among the very successful approaches.

Fluctuation theorem for irreversible entropy production in electrical conduction.

Linear irreversible thermodynamics predicts that the entropy production rate can become negative. We demonstrate this prediction for metals under AC driving whose conductivity is well described by the Drude-Sommerfeld model. We then show that these negative rates are fully compatible with stochastic thermodynamics, namely, that the entropy production does fulfill a fluctuation theorem.

Negative entropy production rates in Drude-Sommerfeld metals.

It is commonly accepted that in typical situations the rate of entropy production is non-negative. We show that this assertion is not entirely correct, not even in the linear regime, if a time-dependent, external perturbation is not compensated by a rapid enough decay of the response function. This is demonstrated for three variants of the Drude model to describe electrical conduction in noble metals, namely the classical free electron gas, the Drude-Sommerfeld model, and the extended Drude-Sommerfeld model.

Microcanonical Szilárd engines beyond the quasistatic regime.

We discuss the possibility of extracting energy from a single thermal bath using microcanonical Szilárd engines operating in finite time. This extends previous works on the topic which are restricted to the quasistatic regime. The feedback protocol is implemented based on linear response predictions of the excess work.

Conditional reversibility in nonequilibrium stochastic systems.

For discrete-state stochastic systems obeying Markovian dynamics, we establish the counterpart of the conditional reversibility theorem obtained by Gallavotti for deterministic systems [Ann. de l'Institut Henri Poincaré (A) 70, 429 (1999)]. Our result states that stochastic trajectories conditioned on opposite values of entropy production are related by time reversal, in the long-time limit.

Shortcuts to adiabaticity from linear response theory.

A shortcut to adiabaticity is a finite-time process that produces the same final state as would result from infinitely slow driving. We show that such shortcuts can be found for weak perturbations from linear response theory. With the help of phenomenological response functions, a simple expression for the excess work is found-quantifying the nonequilibrium excitations.

Degenerate optimal paths in thermally isolated systems.

We present an analysis of the work performed on a system of interest that is kept thermally isolated during the switching of a control parameter. We show that there exists, for a certain class of systems, a finite-time family of switching protocols for which the work is equal to the quasistatic value. These optimal paths are obtained within linear response for systems initially prepared in a canonical distribution.

Optimal driving of isothermal processes close to equilibrium.

We investigate how to minimize the work dissipated during nonequilibrium processes. To this end, we employ methods from linear response theory to describe slowly varying processes, i.e.

Relaxation in finite and isolated classical systems: an extension of Onsager's regression hypothesis.

In order to derive the reciprocity relations, Onsager formulated a relation between thermal equilibrium fluctuations and relaxation widely known as regression hypothesis. It is shown in the present work how such a relation can be extended to finite and isolated classical systems. This extension is derived from the fluctuation-dissipation theorem for the microcanonical ensemble.

Lyapunov decoherence rate in classically chaotic systems.

We provide a path integral treatment of the decoherence process induced by a heat bath on a single particle whose dynamics is classically chaotic and show that the decoherence rate is given by the Lyapunov exponent. The loss of coherence is charaterized by the purity, which is calculated semiclassically within diagonal approximation, when the particle initial state is a single Gaussian wave packet. The calculation is performed for weak dissipation and in the high-temperature limit.

Fluctuation-dissipation theorem for the microcanonical ensemble.

A derivation of the fluctuation-dissipation theorem for the microcanonical ensemble is presented using linear response theory. The theorem is stated as a relation between the frequency spectra of the symmetric correlation and response functions. When the system is not in the thermodynamic limit, this result can be viewed as an extension of the fluctuation-dissipation relations to a situation where dynamical fluctuations determine the response.