Correction: Simple synthetic access to [Au(IBiox)Cl] complexes.

Correction for 'Simple synthetic access to [Au(IBiox)Cl] complexes' by Ekaterina A. Martynova , , 2023, , 7558-7563, https://doi.org/10.

Methylene C(sp )-H Arylation Enables the Stereoselective Synthesis and Structure Revision of Indidene Natural Products.

The divergent synthesis of two indane polyketides of the indidene family, namely (±)-indidene A (11 steps, 1.7 %) and (+)-indidene C (13 steps, 1.3 %), is reported.

Effect of α-Substitution on the Reactivity of C(sp)-H Bonds in Pd-Catalyzed C-H Arylation.

We report mechanistic studies on the reactivity of different α-substituted C(sp)-H bonds, -CHR (R = H, Me, COMe, CONMe, OMe, and Ph, as well as the cyclopropyl and isopropyl derivatives -CH(CH) and -CHMe) in the context of Pd-catalyzed C(sp)-H arylation. Primary kinetic isotope effects, /, were determined experimentally for R = H (3.2) and Me (3.

Simple synthetic access to [Au(IBiox)Cl] complexes.

Green and sustainable access to chiral and achiral gold-IBiox complexes is reported. The gold complexes were synthesized using a simple, air-tolerant, weak base protocol carried out in a green solvent. Their catalytic activity was examined in the hydroamination of alkynes.

Palladium(0)-Catalyzed Enantioselective Intramolecular Arylation of Enantiotopic Secondary C-H Bonds.

The enantioselective functionalization of nonactivated enantiotopic secondary C-H bonds is one of the greatest challenges in transition-metal-catalyzed C-H activation proceeding by an inner-sphere mechanism. Such reactions have remained elusive within the realm of Pd catalysis. Reported here is the unique reactivity profile of the IBiox ligand family in the Pd -catalyzed intramolecular arylation of such nonactivated secondary C-H bonds.