The Desiccation and Catastrophic Refilling of the Mediterranean: 50 Years of Facts, Hypotheses, and Myths Around the Messinian Salinity Crisis.

According to some authors, the Messinian salinity crisis was ended by a giant waterfall or megaflood 5.33 million years ago, when the Atlantic Ocean reconnected in a catastrophic way with the desiccated Mediterranean, creating the Strait of Gibraltar. An erosional surface deeply cutting upper Miocene or older rocks and sealed by lower Pliocene sediments is the geological feature that inspired this fascinating hypothesis.

A Markovian model for the spread of the SARS-CoV-2 virus.

We propose a Markovian stochastic approach to model the spread of a SARS-CoV-2-like infection within a closed group of humans. The model takes the form of a Partially Observable Markov Decision Process (POMDP), whose states are given by the number of subjects in different health conditions. The model also exposes the different parameters that have an impact on the spread of the disease and the various decision variables that can be used to control it (e.

Stone/Coating Interaction and Durability of Si-Based Photocatalytic Nanocomposites Applied to Porous Lithotypes.

The use of hybrid nanocoatings for the protection of natural stones has received increasing attention over the last years. However, the interaction of these materials with stones and, in particular, its modification resulting from the blending of nanoparticles and matrices, are yet little explored. In this work, the interaction of two nanocomposite coatings (based on alkylalkoxysilane matrices and TiO₂ nanoparticles in water and 2-propanol) with two different porous stones is examined in detail by comparing their absorption behaviour and protection performance with those of the respective TiO₂-free matrices.

Photocatalytic Nanocomposites for the Protection of European Architectural Heritage.

In the field of stone protection, the introduction of inorganic nanoparticles, such as TiO₂, ZnO, and Ag in polymeric blends can enhance the protective action of pristine treatments, as well as confer additional properties (photocatalytic, antifouling, and antibacterial). In the framework of the "Nano-Cathedral" European project, nanostructured photocatalytic protective treatments were formulated by using different TiO₂ nanoparticles, solvents, and silane/siloxane systems in the blends. The results about the characterization and application of two promising nano-TiO₂ based products applied on Apuan marble and Ajarte limestone are here reported, aiming at investigating the complex system "treatment/stone-substrate".