Publications by authors named "Marco Coisson"

Magnetostrictive materials are essential components in sensors, actuators, and energy-storage devices due to their ability to convert mechanical stress into changes in magnetic properties and vice-versa. However, their operation typically requires physical contact to apply stress or relies on magnetic field sources to control magnetic properties. This poses significant limitations to devices miniaturization and their integration into contactless technologies.

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Magnetically responsive soft biomaterials are at the forefront of bioengineering and biorobotics. We have created a magnetic hybrid material by coupling silk fibroin─i.e.

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The detection of magnetic nanoparticles in a liquid medium and the quantification of their concentration have the potential to improve the efficiency of several relevant applications in different fields, including medicine, environmental remediation, and mechanical engineering. To this end, sensors based on the magneto-impedance effect have attracted much attention due to their high sensitivity to the stray magnetic field generated by magnetic nanoparticles, their simple fabrication process, and their relatively low cost. To improve the sensitivity of these sensors, a multidisciplinary approach is required to study a wide range of soft magnetic materials as sensing elements and to customize the magnetic properties of nanoparticles.

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The connection of multidisciplinary and versatile techniques capable of depositing and modeling thin films in multistep complex fabrication processes offers different perspectives and additional degrees of freedom in the realization of patterned magnetic materials whose peculiar physical properties meet the specific needs of several applications. In this work, a fast and cost-effective dealloying process is combined with a fast, low-cost, scalable electroless deposition technique to realize hybrid magnetic heterostructures. The gold nanoporous surface obtained by the dealloying of an AuSiCuAgPd ribbon is used as a nanostructured substrate for the electrodeposition of cobalt.

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Dense and mesoporous FePd nanowires (NWs) with 45 to 60 at.% Pd content were successfully fabricated by template- and micelle-assisted pulsed potentiostatic electrodeposition using nanoporous anodic alumina and polycarbonate templates of varying pore sizes. An FePd electrolyte was utilized for obtaining dense NWs while a block copolymer, P-123, was added to this electrolyte as the micelle-forming surfactant to produce mesoporous NWs.

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Magnetic hyperthermia is an oncological therapy that exploits magnetic nanoparticles activated by radiofrequency magnetic fields to produce a controlled temperature increase in a diseased tissue. The specific loss power (SLP) of magnetic nanoparticles or the capability to release heat can be improved using surface treatments, which can reduce agglomeration effects, thus impacting on local magnetostatic interactions. In this work, FeO nanoparticles are synthesized via a coprecipitation reaction and fully characterized in terms of structural, morphological, dimensional, magnetic, and hyperthermia properties (under the Hergt-Dutz limit).

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Flexible materials have brought up a new era of application-based research in stretchable electronics and wearable devices in the last decade. Tuning of magnetic properties by changing the curvature of devices has significant impact in the new generation of sensor-based technologies. In this work, magnetostrictive FeGa thin films have been deposited on a flexible Kapton sheet to exploit the magneto-elastic coupling effect and modify the magnetic properties of the sample.

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Advances in nanofabrication techniques are undoubtedly needed to obtain nanostructured magnetic materials with physical and chemical properties matching the pressing and relentless technological demands of sensors. Solid-state dewetting is known to be a low-cost and "top-down" nanofabrication technique able to induce a controlled morphological transformation of a continuous thin film into an ordered nanoparticle array. Here, magnetic Fe70Pd30 thin film with 30 nm thickness is deposited by the co-sputtering technique on a monocrystalline (MgO) or amorphous (Si3N4) substrate and, subsequently, annealed to promote the dewetting process.

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The ability of magnetic nanoparticles (MNPs) to transform electromagnetic energy into heat is widely exploited in well-known thermal cancer therapies, such as magnetic hyperthermia, which proves useful in enhancing the radio- and chemo-sensitivity of human tumor cells. Since the heat release is ruled by the complex magnetic behavior of MNPs, a careful investigation is needed to understand the role of their intrinsic (composition, size and shape) and collective (aggregation state) properties. Here, the influence of geometrical parameters and aggregation on the specific loss power (SLP) is analyzed through in-depth structural, morphological, magnetic and thermometric characterizations supported by micromagnetic and heat transfer simulations.

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FePd alloys in the thin film form represent a multipurpose and versatile material with relevant chemical and physical properties studied in different research fields. Moreover, the ability to manipulate and fine-tune the film surface with nanometric scale precision represents a degree of freedom useful to adapt these thin film properties to the demands of different desired applications. In this manuscript, FePd (at.

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Sputtering and electrodeposition are among the most widespread techniques for metallic thin film deposition. Since these techniques operate under different principles, the resulting films typically show different microstructures even when the chemical composition is kept fixed. In this work, films of FePd were produced in a thickness range between 30 and 600 nm, using both electrodeposition and sputtering.

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An important research effort on the design of the magnetic particles is increasingly required to optimize the heat generation in biomedical applications, such as magnetic hyperthermia and heat-assisted drug release, considering the severe restrictions for the human body's exposure to an alternating magnetic field. Magnetic nanoparticles, considered in a broad sense as passive sensors, show the ability to detect an alternating magnetic field and to transduce it into a localized increase of temperature. In this context, the high biocompatibility, easy synthesis procedure and easily tunable magnetic properties of ferrite powders make them ideal candidates.

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Bimetallic nanomaterials in the form of thin film constituted by magnetic and noble elements show promising properties in different application fields such as catalysts and magnetic driven applications. In order to tailor the chemical and physical properties of these alloys to meet the applications requirements, it is of great importance scientific interest to study the interplay between properties and morphology, surface properties, microstructure, spatial confinement and magnetic features. In this manuscript, FePd thin films are prepared by electrodeposition which is a versatile and widely used technique.

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We present a detailed study of permalloy (NiFe) nanostructures with variable shape (disk, cylinder and sphere) for magnetic hyperthermia application, exploiting hysteresis losses for heat release. The study is performed modifying nanostructure aspect ratio and size (up to some hundreds of nanometres), to find the optimal conditions for the maximization of specific heating capabilities. The parameters are also tuned to guarantee negligible magnetic remanence and fulfilment of biophysical limits on applied field amplitude and frequency product, to avoid aggregation phenomena and intolerable resistive heating, respectively.

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Multicomponent layered systems with tailored magnetic properties were fabricated via current annealing from homogeneous FePd thin films, deposited via radio frequency sputtering on Si/SiO2 substrates from composite target. To promote spontaneous nano-structuring and phase separation, selected samples were subjected to current annealing in vacuum, with a controlled oxygen pressure, using various current densities for a fixed time and, as a consequence, different phases and microstructures were obtained. In particular, the formation of magnetite in different amount was observed beside other iron oxides and metallic phases.

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A bi-component nanostructured system composed by a Co dot array embedded in a NiFe antidot matrix has been prepared by means of the self-assembling polystyrene nanospheres lithography technique. Reference samples constituted by the sole Co dots or NiFe antidots have also been prepared, in order to compare their properties with those of the bi-component material. The coupling between the two ferromagnetic elements has been studied by means of magnetic and magneto-transport measurements.

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Background: Magnetic hysteresis loops areas and hyperthermia on magnetic nanoparticles have been studied with the aim of providing reliable and reproducible methods of measuring the specific absorption rate (SAR).

Methods: The SAR of FeO nanoparticles with two different mean sizes, and NiZnFeO ferrites with 0 ≤ x ≤ 0.8 has been measured with three approaches: static hysteresis loops areas, dynamic hysteresis loops areas and hyperthermia of a water solution.

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Nanoscale magnetic materials are the basis of emerging technologies to develop novel magnetoelectronic devices. Self-assembly of polystyrene nanospheres is here used to generate 2D hexagonal dot arrays on FePd thin films. This simple technique allows a wide-area patterning of a magnetic thin film.

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Magnetic vortex chirality in patterned square dots has been investigated by means of a field-dependent magnetic force microscopy technique that allows to measure local hysteresis loops. The chirality affects the two loop branches independently, giving rise to curves that have different shapes and symmetries as a function of the details of the magnetisation reversal process in the square dot, that is studied both experimentally and through micromagnetic simulations. The tip-sample interaction is taken into account numerically, and exploited experimentally, to influence the side of the square where nucleation of the vortex preferably occurs, therefore providing a way to both measure and drive chirality with the present technique.

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This paper studies, from a modelling point of view, the influence of randomly distributed lattice defects (non-patterned areas and variable hole size) on the ferromagnetic resonance behaviour and spin wave mode profiles of 2D magnonic crystals based on Ni80Fe20 antidot arrays with hexagonal lattice. A reference sample is first defined via the comparison of experimental and simulated hysteresis loops and magnetoresistive curves of patterned films, prepared by self-assembly of polystyrene nanospheres. Second, a parametric analysis of the dynamic response is performed, investigating how edge, quasi-uniform and localized modes are affected by alterations of the lattice geometry and bias field amplitude.

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Article Synopsis
  • Nanoscale zerovalent iron (NZVI) shows promise for degrading environmental pollutants but faces challenges due to particle aggregation, which reduces its effectiveness and movement.
  • This study uses an alternating gradient force magnetometer (AGFM) to analyze the magnetic properties of NZVI, finding that the particles do not behave in a superparamagnetic way due to the aggregation.
  • The research adopts an extended Stoner-Wohlfarth model to account for interactions among the particles and concludes that magnetic forces dominate over electrostatic repulsion in this context.
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