Investigation of the Origin of High Photoluminescence Quantum Yield in Thienyl-S,S-dioxide AIEgens Oligomers by Temperature Dependent Optical Spectroscopy.

The development of organic molecules showing high photoluminescence quantum yield (PLQY) in solid state is a fundamental step for the implementation of efficient light emitting devices. In this work the origin of the high PLQY of two trimers and two pentamers having one central thiophene-S,S-dioxide unit and two and four lateral thiophene or phenyl groups, respectively, is investigated by temperature dependent photoluminescence and time resolved photoluminescence measurements. The experimental results demonstrate that the molecules with lateral phenyl rings show higher PLQY due to a weaker coupling with intramolecular vibrations-related to variations in the radiative and non-radiative decay rates-and indicate different molecular rigidity as the main factors affecting the PLQY of this class of molecules.

Temperature-Dependent Amplified Spontaneous Emission in CsPbBr Thin Films Deposited by Single-Step RF-Magnetron Sputtering.

Due to their high optical efficiency, low-cost fabrication and wide variety in composition and bandgap, halide perovskites are recognized nowadays as real contenders for the development of the next generation of optoelectronic devices, which, among others, often require high quality over large areas which is readily attainable by vacuum deposition. Here, we report the amplified spontaneous emission (ASE) properties of two CsPbBr films obtained by single-step RF-magnetron sputtering from a target containing precursors with variable compositions. Both the samples show ASE over a broad range of temperatures from 10 K up to 270 K.

Investigation of the exciton relaxation processes in poly(9,9-dioctylfluorene--benzothiadiazole):CsPbIBr nanocrystal hybrid polymer-perovskite nanocrystal blend.

The combination of lead halide perovskite nanocrystals and conjugated polymer in a blend film opens the way to the realization of hybrid active layers with widely tunable optical and electrical properties. However, the interaction between the polymeric and the perovskite component of the blends is mainly unexplored to date. In this work we perform temperature-dependent photoluminescence and time resolved photoluminescence measurements in order to deeply investigate the photophysics of a poly(9,9-dioctylfluorene--benzothiadiazole) (F8BT):CsPbIBr nanocrystal hybrid film.

Light Emission Properties of Thermally Evaporated CHNHPbBr Perovskite from Nano- to Macro-Scale: Role of Free and Localized Excitons.

Over the past decade, interest about metal halide perovskites has rapidly increased, as they can find wide application in optoelectronic devices. Nevertheless, although thermal evaporation is crucial for the development and engineering of such devices based on multilayer structures, the optical properties of thermally deposited perovskite layers (spontaneous and amplified spontaneous emission) have been poorly investigated. This paper is a study from a nano- to micro- and macro-scale about the role of light-emitting species (namely free carriers and excitons) and trap states in the spontaneous emission of thermally evaporated thin layers of CHNHPbBr perovskite after wet air UV light trap passivation.

Local Morphology Effects on the Photoluminescence Properties of Thin CsPbBr Nanocrystal Films.

Lead halide perovskites are emerging as extremely interesting active materials for a wide variety of optoelectronic and photonic devices. A deep understanding of their photophysics is thus fundamental in order to properly understand the origins of the materials active properties and to provide strategies for improving them. In this work, we exploit the local morphological variations in a drop-cast thin CsPbBr3 nanocrystal film to show that the aggregation of NCs has strong effects on the peak wavelengths of PL spectra, the linewidth, and the intensity of dependence on temperature.

Special Issue "II-VI Semiconductor Nanocrystals and Hybrid Polymer-Nanocrystal Systems".

The continuous need to improve the performance of photonic, electronic and optoelectronic devices has stimulated research toward the development of innovative semiconducting materials which display better properties with respect to standard bulk semiconductors [...

Environment-Induced Reversible Modulation of Optical and Electronic Properties of Lead Halide Perovskites and Possible Applications to Sensor Development: A Review.

Lead halide perovskites are currently widely investigated as active materials in photonic and optoelectronic devices. While the lack of long term stability actually limits their application to commercial devices, several experiments demonstrated that beyond the irreversible variation of the material properties due to degradation, several possibilities exist to reversibly modulate the perovskite characteristics by acting on the environmental conditions. These results clear the way to possible applications of lead halide perovskites to resistive and optical sensors.

Deep Blue Light Amplification from a Novel Triphenylamine Functionalized Fluorene Thin Film.

The development of high performance optically pumped organic lasers operating in the deep blue still remains a big challenge. In this paper, we have investigated the photophysics and the optical gain characteristics of a novel fluorene oligomer functionalized by four triphenylamine (TPA) groups. By ultrafast spectroscopy we found a large gain spectral region from 420 to 500 nm with a maximum gain cross-section of 1.

Amplified Spontaneous Emission Threshold Reduction and Operational Stability Improvement in CsPbBr Nanocrystals Films by Hydrophobic Functionalization of the Substrate.

The use of lead halide perovskites in optoelectronic and photonic devices is mainly limited by insufficient long-term stability of these materials. This issue is receiving growing attention, mainly owing to the operational stability improvement of lead halide perosvkites solar cells. On the contrary, fewer efforts are devoted to the stability improvement of light amplification and lasing.

Colloidal CdSe Quantum Wells with Graded Shell Composition for Low-Threshold Amplified Spontaneous Emission and Highly Efficient Electroluminescence.

Semiconductor nanoplatelets (NPLs) have emerged as a very promising class of colloidal nanocrystals for light-emitting devices owing to their quantum-well-like electronic and optical characteristics. However, their lower photoluminescence quantum yield (PLQY) and limited stability have hampered the realization of their outstanding luminescent properties in device applications. Here, to address these deficiencies, we present a two-step synthetic approach that enables the synthesis of core/shell NPLs with precisely controlled shell composition for engineering their excitonic properties.

Polymer-II-VI Nanocrystals Blends: Basic Physics and Device Applications to Lasers and LEDs.

Hybrid thin films that combine organic conjugated molecules and semiconductors nanocrystals (NCs) have been deeply investigated in the previous years, due to their capability to provide an extremely broad tuning of their electronic and optical properties. In this paper we review the main aspects of the basic physics of the organic-inorganic interaction and the actual state of the art of lasers and light emitting diodes based on hybrid active materials.

Random Lasing Engineering in Poly-(9-9dioctylfluorene) Active Waveguides Deposited on Wrinkles Corrugated Surfaces.

This paper investigates the correlation between the random lasing properties of organic waveguides made by poly-(9-9dioctylfluorene) (PFO) thin films and the morphology of wrinkled corrugated substrates. The capability to individually control the wrinkle wavelength, shape, and height allows us to separately investigate their role on the sample emission properties. We demonstrate that the main parameter determining the presence of coherent random lasing is the substrate roughness and that, contrary to what could be qualitatively expected, as the roughness increases, coherent random lasing is progressively reduced.

Bright oligothiophene N-succinimidyl esters for efficient fluorescent labeling of proteins and oligonucleotides.

The synthesis of multicolor fluorescent oligothiophene N-succinimidyl esters (TSEs) is reported, and their optical properties are discussed with the aid of ab initio calculations. The esters were coupled to proteins and to 3'-amino-modified oligonucleotides in mild conditions and with similar modalities. A comparative study of the bioconjugate of IgG1 anti-CD3 antibody labeled with a blue fluorescent TSE and with fluorescein isothiocyanate (FITC) is reported, showing that the former achieves higher photoluminescence intensity and optical stability than the latter.