Surface water and groundwater interaction in the Vredefort Dome, South Africa: a stable isotope and multivariate statistical approach.

The growing importance of groundwater as a freshwater supply in semi-arid areas such as the Vredefort Dome World Heritage Site (VDWHS) demands the judicious management and development of this vital resource. The increased demand for groundwater due to the contamination of surface water, coupled with the lack of information on hydrological interaction and associated water quality implications, present difficulties in establishing management strategies. An integrated study based on hydrochemistry and multivariate statistical techniques supplemented by environmental isotopes delineated discrete areas of surface water and groundwater interaction in a fractured-rock terrain.