Spectrochim Acta A Mol Biomol Spectrosc
December 2024
Herein, high-efficiency green fluorescence nitrogen doped CDs (G-CDs) were prepared using acetaminophen and ethylenediamine as precursors. The G-CDs exhibited good anti-photobleaching, salttolerance and low cytotoxicity. Interestingly, the G-CDs revealed excellent fluorescence stability in the pH range of 6-12, however, the intensity of the G-CDs was almost completely quenched in other pH values.
View Article and Find Full Text PDFA highly sensitive ultra-small ratiometric fluorescence nanosphere probe was successfully manufactured to detect Sunset Yellow (SY). The probe, CMCS@N, S-CDs/Rh6G, was formed through the encapsulation of N, S-CDs and Rh6G within carboxymethyl chitosan (CMCS) through in situ cross-linking. Remarkably, our nanosphere probe had an average grain diameter of 6.
View Article and Find Full Text PDFSanmen Bay plays a crucial role in economic shellfish aquaculture in China, yet few studies exist on the arsenic speciation of shellfish from this area. In this study, arsenic speciation of 11 cultured shellfish species from Sanmen Bay were analyzed by HPLC/ICP-MS. The results showed that organic arsenic particularly AsB, was the dominant arsenic species, constituting 21 %-71 % of the total arsenic.
View Article and Find Full Text PDFThis study analyzed the cadmium accumulation differences in edible tissues of the swimming crabs (Portunus trituberculatus) from Shanghai markets, which were mostly caught in the East China Sea, and the human health risk of cadmium from crabs consumption was evaluated. A total of 78 swimming crabs were collected, and the white meat and brown meat were separated for the cadmium analysis by Inductively coupled plasma mass spectrometry. The results revealed that there was difference in cadmium content in brown meat (1.
View Article and Find Full Text PDFTetracycline (TC) is widely used as a veterinary drug, and its residue in livestock products could enter the human body and cause damage. In this study, we developed an eco-friendly approach that utilized pomelo peel as a carbon source to synthesize new water-soluble N-doped carbon dots (P-NCDs) with blue fluorescence, obtaining a high quantum yield of up to 76.47% and achieving the goal of turning waste into value.
View Article and Find Full Text PDFInflammation and fibrosis induced by hyperglycemia are considered to play a critical role in the pathogenesis of diabetic nephropathy. As macrophage polarization may determine the severity and progression of inflammation, regulation of macrophage polarization may be an effective method to treat diabetic complications. Fasudil, a potent Rho-kinase inhibitor, reportedly exhibits anti-inflammatory activity.
View Article and Find Full Text PDFJ Colloid Interface Sci
August 2020
Through direct addition of inorganic zinc ions into the solution of indium phosphide quantum dots (InP QDs) at ambient environment, we here present a facile but effective method to modify InP QDs for photocatalytic hydrogen evolution from hydrogen sulfide (HS). X-ray diffraction patterns and transmission electron microscopic images demonstrate that zinc ions have no significant influence on the crystal structure and morphology of InP QDs, while X-ray photoemission spectra and UV-Vis diffuse and reflectance spectra indicate that zinc ions mainly adsorbed on the surface of InP QDs. Photocatalytic results show the average hydrogen evolution rate has been enhanced to 2.
View Article and Find Full Text PDFIn order to remedy the current problem of having been buffeted by competing requirements for both protection sensitivity and quick reaction of High Voltage Direct Current (HVDC) transmission lines simultaneously, a new intelligent fault identification method based on Random Forests (RF) for HVDC transmission lines is proposed. S transform is implemented to extract fault current traveling wave of 8 frequencies and calculate the fluctuation index and energy sum ratio, in which the wave index is used to identify internal and external faults, and energy sum ratio is used to identify the positive and negative pole faults occurred on the transmission line. The intelligent fault identification model of RF is established, and the fault characteristic sample set of HVDC transmission lines is constructed by using multi-scale S transform fluctuation index and multi-scale S-transform energy sum ratio.
View Article and Find Full Text PDFAn accurate, rapid signal analysis is crucial in the acoustic-based detection for internal defects in arc magnets. Benefiting from the adaptive decomposition without the mode mixing, variational mode decomposition (VMD), has emerged as a promising technology for processing and analyzing acoustic signals. However, improper parameter settings are the root cause of inaccurate VMD results, while existing optimization methods for VMD parameters are only applicable to a single signal with exclusive signal characteristics, rather than different signals with similar features.
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